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Article Dans Une Revue Chemical Communications Année : 2020

Hydrogen evolution reaction mediated by an all-sulfur trinuclear nickel complex

Résumé

We report the synthesis and the characterization of a trinuclear nickel complex. Solid state and solution studies using X-ray diffraction, NMR and UV-vis spectroscopy highlight the square planar geometries around the metal centers and an all-sulfur coordination sphere. It exhibits significant electrocatalytic activity for hydrogen evolution in DMF using Et3NHCl as the proton source. DFT studies suggest that sulfur atoms act as proton relay, as proposed in [NiFe] hydrogenases.
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Dates et versions

hal-02961657 , version 1 (17-11-2020)

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Cyril Pieri, Anirban Bhattacharjee, Alexandre Barrozo, Bruno Faure, Michel Giorgi, et al.. Hydrogen evolution reaction mediated by an all-sulfur trinuclear nickel complex. Chemical Communications, 2020, 56 (75), pp.11106-11109. ⟨10.1039/d0cc04174b⟩. ⟨hal-02961657⟩
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