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Hexaarm star-shaped polystyrenes by core-first method

Abstract : The hexafunctional initiator C6[(CH2)2p-C6H4CH(Cl)Me]6 is synthesized by Fe(η-C5H5)+ induced hexabenzylation of C6Me6 followed by regiospecific acetylation, NaBH4 reduction and chlorination, and allows the living cationic polymerization of styrene which yields hexaarm star-shaped polymers.
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Contributor : Eric Cloutet Connect in order to contact the contributor
Submitted on : Friday, September 4, 2020 - 1:57:59 PM
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Eric Cloutet, Jean-Luc Fillaut, Yves Gnanou, Didier Astruc. Hexaarm star-shaped polystyrenes by core-first method. Journal of the Chemical Society, Chemical Communications, Royal Society of Chemistry, 1994, pp.2433. ⟨10.1039/C39940002433⟩. ⟨hal-02930419⟩



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