Proton conduction study of a new selenate-based hybrid compound

Dhouha Abid (1) , Ikram Dhouib (1) , Philippe Guionneau (2) , Stanislav Pechev (2) , Iskandar Chaabane (3) , Nathalie Daro (2) , Zakaria Elaoud (1)

1 Laboratoire Physicochimie de l'Etat Solide
2 ICMCB - Institut de Chimie de la Matière Condensée de Bordeaux
3 FSS - Faculté des Sciences de Sfax

Ongoing studies aimed at developing a novel proton conducting solids, resulted in the new organic-inorganic compound [(C2H5)4N] HSeO4 (H2SeO4)2. The crystals were prepared by slow evaporation technique at room temperature. Crystal structure, thermal and electrical measurements were provided to characterize this compound. Single-crystal X-ray study showed that the new phase crystallizes belongs to the Cc space group of the monoclinic system with lattice parameters: a = 19.705 (1) Å; b = 7.5420 (3) Å; c = 19.199 (1) Å, β = 115°. The structure consists of infinite two-dimensional inter-linkers via strong hydrogen bonds (O–H⋯O) giving birth to trimers. Two phase transition were disclosed by differential thermal analysis and confirmed by electrical measurements and dielectric measurements. The complex impedance of the compound was investigated in the temperature range 290–373 K and in the frequency range 1-13.103 KHz. Besides, an electrical equivalent circuit was proposed to explain the impedance results. Electric and dielectric analyses reveal the presence of a relaxation phenomenon and highlight the good protonic conduction of this material.

Mots clés: Complex impedance; Hydrogen bond; Organic-inorganic material; Crystal structure; Proton conduction; Electric and dielectric analysis

Domaines: Matériaux

Dhouha Abid, Ikram Dhouib, Philippe Guionneau, Stanislav Pechev, Iskandar Chaabane, et al.. Proton conduction study of a new selenate-based hybrid compound. Journal of Alloys and Compounds, 2020, 824, pp.153826. ⟨10.1016/j.jallcom.2020.153826⟩. ⟨hal-02639224⟩