Skip to Main content Skip to Navigation
Journal articles

Mechano-electric coupling in P(VDF–TrFE)/spin crossover composites

Abstract : Spin crossover particles dispersed in a piezo/ferroelectric poly(vinylidene fluoride-co-trifluoro-ethylene), P(VDF–TrFE), matrix give rise to inspiring mechano-electric phenomena, with possible applications for energy harvesting and sensing. Particles of different chemical compositions, morphologies and concentrations were loaded into copolymers with different TrFE molar contents to investigate the effect of these parameters on the mechano-electric coupling between the polymer and the spin crossover material. The samples were characterized by elemental analysis, powder X-ray diffraction, Raman spectroscopy, optical reflectivity, differential scanning calorimetry, and electron microscopy and were studied also for their piezo/pyroelectric properties. We show that it is possible to tune simultaneously the spin transition temperature of the particles and the Curie temperature of the matrix in such a way that the piezoelectric effect from the spin transition and the pyroelectric response of the polymer can be concomitantly observed. This result provides prospects for the development of smart, multifunctional electroactive polymer composites and for increasing their thermal–electrical harvester output.
Document type :
Journal articles
Complete list of metadata

Cited literature [30 references]  Display  Hide  Download
Contributor : Marie-Hélène Gulli <>
Submitted on : Friday, June 26, 2020 - 2:31:35 PM
Last modification on : Tuesday, May 4, 2021 - 3:33:40 PM


Files produced by the author(s)




Mario Piedrahita-Bello, Baptiste Martin, Lionel Salmon, Gábor Molnár, Philippe Demont, et al.. Mechano-electric coupling in P(VDF–TrFE)/spin crossover composites. Journal of Materials Chemistry C, Royal Society of Chemistry, 2020, 8 (18), pp.6042-6051. ⟨10.1039/d0tc00780c⟩. ⟨hal-02571024⟩



Record views


Files downloads