Ion release characterization in phase separated borosilicate glass powders

Federico Lizzi (1, 2) , Christelle Goutaudier (1) , Nina Attik (1, 3) , Philip Jackson (2) , Ian Campbell (2) , Ilham Mokbel (1) , Brigitte Grosgogeat (1, 4, 3) , Cyril Villat (1, 4, 3)

1 LMI - Laboratoire des Multimatériaux et Interfaces
2 Lucideon
3 UFR d’Odontologie, Université de Lyon,
4 Service d'Odontologie Hospices Civils de Lyon

A series of novel borosilicate ionomer glasses composed of varying amount of SiO2–B2O3–K2OeCaO–Al2O3 wereinvestigated. The influence of the thermal treatment was evaluated in terms of ion release and glass microstructure.Inductively coupled plasma optical emission spectrometry (ICP-OES) and scanning electron microscopy(SEM) were the main analytical techniques used in this study. The results show that all the glasses sampleswere amorphous according to the XRD and the SEM results before and after the heat-treatment. However, whilstthe as-quenched samples appeared consistently transparent and colourless, the thermal treatment at 700 °C for20 h induced some of the samples to turn opalescent. The ion concentration profiles suggest that the dissolutionrate of Ca and B were enhanced by the heat treatment in all cases. Moreover, it was confirmed that differentleaching rates exist between the opal and clear samples

Mots clés: Borosilicate glass; Phase separation; Characterization; Ion release; Al-free glass powder

Domaines: Chimie; Matériaux; Biomatériaux; Cristallographie

Federico Lizzi, Christelle Goutaudier, Nina Attik, Philip Jackson, Ian Campbell, et al.. Ion release characterization in phase separated borosilicate glass powders. Journal of Non-Crystalline Solids, 2020, 534, pp.119934. ⟨10.1016/j.jnoncrysol.2020.119934⟩. ⟨hal-02545840⟩