G. B. Kauffman, The discovery of ferrocene, the first sandwich compound, J Chem Educ, vol.60, pp.185-186, 1983.

T. J. Kealy and P. L. Pauson, A new type of organo-iron compound, Nature, vol.168, pp.1039-1040, 1951.

S. A. Miller, J. A. Tebboth, J. F. Tremaine, and D. , J Chem Soc, vol.0, pp.632-635, 1952.

H. Werner, At least 60 years of ferrocene: the discovery and rediscovery of the sandwich complexes, Angew Chem Int Ed, vol.51, pp.6052-6058, 2012.

D. Astruc, Why is ferrocene so exceptional?, Eur J Inorg Chem, vol.1, pp.6-29, 2017.

R. R. Gagne, C. A. Koval, and G. C. Lisensky, Ferrocene as an internal standard for electrochemical measurements, Inorg Chem, vol.19, pp.2854-2855, 1980.

F. Bures, Fundamental aspects of property tuning in push-pull molecules, RSC Adv, vol.4, pp.58826-58851, 2014.

X. Xia, H. Yu, L. Wang, and Z. U. Abdin, Recent progress in ferrocene-and azobenzene based photoelectric responsive materials, RSC Adv, vol.6, pp.105296-105316, 2016.

A. M. El-zohry, J. Cong, M. Karlsson, L. Kloo, and B. Zietz, Ferrocene as a rapid charge regenerator in dye-sensitized solar cells, Dyes Pigments, vol.132, pp.360-368, 2016.

T. Daeneke, T. Kwon, A. B. Holmes, N. W. Duffy, U. Bach et al., High-efficiency dye-sensitized solar cells with ferrocene-based electrolytes, Nat Chem, vol.3, pp.211-215, 2011.

Y. Patil, R. Misra, R. Singhal, and G. D. Sharma, Ferrocene-diketopyrrolopyrrole based non-fullerene acceptors for bulk heterojunction polymer solar cells, J Mater Chem, vol.5, pp.13625-13633, 2017.

Y. Chang, M. Huang, C. Lai, C. Chang, M. Huang et al., A versatile ferrocene-containing material as a p-type charge generation layer for high-performance full color tandem OLEDs, Chem Commun, vol.52, pp.14294-14297, 2016.

N. Y. Shim, D. A. Bernards, D. J. Macaya, J. A. Defranco, M. Nikolou et al., All-plastic electrochemical transistor for glucose sensing using a ferrocene mediator, Sensors, vol.9, pp.9896-9902, 2009.
URL : https://hal.archives-ouvertes.fr/emse-00447490

R. Teimuri-mofrad, K. Rahimpour, R. Ghadari, and S. Ahmadi-kandjani, Ferrocene based nonlinear optical chromophores: synthesis, characterization and study of optical properties, J Mol Liq, vol.244, pp.322-329, 2017.

R. Sun, L. Wang, H. Yu, Z. Abdin, Y. Chen et al., Molecular recognition and sensing based on ferrocene derivatives and ferrocene-based polymers, Organometallics, vol.33, pp.4560-4573, 2014.

M. S. Morad and A. A. Sarhan, Application of some ferrocene derivatives in the field of corrosion inhibition, Corros Sci, vol.50, pp.744-753, 2008.

O. Karagollu, M. Gorur, F. Gode, B. Sennik, and F. Yilmaz, Phosphate ion sensors based on triazole connected ferrocene moieties, Sens Actuators, B, vol.193, pp.788-798, 2014.

J. Lalevée, P. Garra, F. Dumur, D. Gigmes, J. Fouassier et al., Ferrocene-based (photo)redox polymerization under long wavelengths, Polym Chem, 2019.

C. Ornelas, Application of ferrocene and its derivatives in cancer research, New J Chem, vol.35, 1973.

A. Guerlin, F. Dumur, E. Dumas, F. Miomandre, G. Wantz et al., Tunable optical properties of chromophores derived from oligo(p-phenylene vinylene), Org Lett, vol.12, pp.2382-2385, 2010.
URL : https://hal.archives-ouvertes.fr/hal-00585562

M. Tehfe, F. Dumur, B. Graff, F. Morlet-savary, J. Fouassier et al., New push-pull dyes derived from Michler's ketone for polymerization reactions upon visible lights, Macromolecules, vol.46, pp.3761-3770, 2013.

K. S. Egorova and V. P. Ananikov, Toxicity of metal compounds: knowledge and myths, Organometallics, vol.36, pp.4071-4090, 2017.

K. Y. Law, Organic photoconductive materials: recent trends and developments, Chem Rev, vol.93, pp.449-486, 1993.

L. E. Wilson, C. Hassenrgck, R. F. Winter, A. J. White, T. Albrecht et al., Ferrocene-and biferrocene-containing macrocycles towards single-molecule electronics, Angew Chem Int Ed, vol.56, pp.6838-6842, 2017.

Y. Lin, H. Fan, Y. Li, and X. Zhan, Thiazole-based organic semiconductors for organic electronics, Adv Mater, vol.24, pp.3087-3106, 2012.

S. Chen, Y. Li, W. Yang, N. Chen, H. Liu et al., Synthesis and tuning optical nonlinear properties of molecular crystals of benzothiadiazole, J Phys Chem C, vol.114, pp.15109-15115, 2010.

H. Zhang, X. Wan, X. Xue, Y. Li, A. Yu et al., Selective tuning of the HOMO-LUMO gap of carbazole-based donor-acceptor-donor compounds toward different emission colors, Eur J Org Chem, vol.9, pp.1681-1687, 2010.

X. Liu, S. Li, J. Li, J. Wang, Z. Tan et al., Synthesis, characterization and photovoltaic properties of benzo[1,2-b:4,5-b?]dithiophene-bridged molecules, RSC Adv, vol.4, pp.63260-63267, 2014.

S. Chen, Y. Li, C. Liu, W. Yang, and Y. Li, Strong charge-transfer chromophores from [2+2] cycloadditions of TCNE and TCNQ to peripheral donor-substituted alkynes, Eur J Org Chem, pp.6445-6451, 2011.

W. Li, C. Du, F. Li, Y. Zhou, M. Fahlman et al., Benzothiadiazole-based linear and star molecules: design, synthesis, and their application in bulk heterojunction organic solar cells, Chem Mater, vol.21, pp.5327-5334, 2009.

C. He, Q. He, Y. Yi, G. Wu, F. Bai et al., Improving the efficiency of solution processable organic photovoltaic devices by a star-shaped molecular geometry, J Mater Chem, vol.18, pp.4085-4090, 2008.

H. Shang, H. Fan, Y. Liu, W. Hu, Y. Li et al., A solution-processable star-shaped molecule for high-performance organic solar cells, Adv Mater, vol.23, pp.1554-1557, 2011.

S. Ellinger, K. R. Graham, P. Shi, R. T. Farley, T. T. Steckler et al., Donor-acceptor-donor-based ?-conjugated oligomers for nonlinear optics and near-IR emission, Chem Mater, vol.23, pp.3805-3817, 2011.

R. Misra, P. Gautam, and R. Maragani, Ferrocenyl thiazoles: synthesis and properties, Tetrahedron Lett, vol.56, pp.1664-1666, 2015.

S. Erten-ela, M. D. Ylimaz, B. Icil, Y. Dede, S. Icli et al., A panchromatic boradiazaindacene (BODIPY) sensitizer for dye-sensitized solar cells, Org Lett, vol.10, pp.3299-3302, 2008.

D. Kumaresan, R. P. Thummel, T. Bura, G. Ulrich, and R. Ziessel, Color tuning in new metal-free organic sensitizers (Bodipys) for dye-sensitized solar cells, Chem Eur J, vol.15, pp.6335-6339, 2009.

S. Kolemen, Y. Cakmak, S. Erten-ela, Y. Altay, J. Brendel et al., Solid-state dye-sensitized solar cells using red and near-IR absorbing Bodipy sensitizers, Org Lett, vol.12, pp.3812-3815, 2010.

M. T. Whited, P. I. Djurovich, S. T. Roberts, A. C. Durrell, C. W. Schlenker et al., Singlet and triplet excitation management in a bichromophoric near-infrared-phosphorescent BODIPY-benzoporphyrin platinum complex, J Am Chem Soc, vol.133, pp.88-96, 2011.

J. Lehl, J. Nierengarten, A. Harriman, T. Bura, and R. Ziessel, Artificial light-harvesting arrays: electronic energy migration and trapping on a sphere and between spheres, J Am Chem Soc, vol.134, pp.988-998, 2012.

K. Flavin, K. Lawrence, J. Bartelmess, M. Tasior, C. Navio et al., Synthesis and characterization of boron azadipyrromethene single-wall carbon nanotube electron donor-acceptor conjugates, ACS Nano, vol.5, pp.1198-1206, 2011.

A. Florian, M. J. Mayoral, V. Stepanenko, and G. Fernandez, Alternated stacks of nonpolar oligo(p-phenyleneethynylene)-BODIPY systems, Chem Eur J, vol.18, pp.14957-14961, 2012.

Q. Zheng, G. Xu, and P. Prasad, Conformationally restricted dipyrromethene boron difluoride (BODIPY) dyes: highly fluorescent, multicolored probes for cellular imaging, Chem Eur J, vol.14, pp.5812-5819, 2008.

P. Didier, G. Ulrich, Y. Mely, and R. Ziessel, Improved push-pull-push E-Bodipy fluorophores for two-photon cell-imaging, Org Biomol Chem, vol.7, pp.3639-3642, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00438762

P. A. Bouit, K. Kamada, P. Feneyrou, G. Berginc, L. Toupet et al., Two-photon absorption-related properties of functionalized BODIPY dyes in the infrared range up to telecommunication wavelengths, Adv Mater, vol.21, pp.1151-1154, 2009.
URL : https://hal.archives-ouvertes.fr/hal-01320606

J. Murtagh, D. O. Frimannsson, and D. F. O'shea, Azide conjugatable and pH responsive near-infrared fluorescent imaging probes, Org Lett, vol.11, pp.5386-5389, 2009.

A. Coskun, M. Yilmaz, and E. U. Akkaya, Bis(2-pyridyl)-substituted boratriazaindacene as an NIR-emitting chemosensor for Hg(II), Org Lett, vol.9, pp.607-609, 2007.

J. Han, A. Loudet, R. Barhoumi, R. C. Burghardt, and K. Burgess, A ratiometric pH reporter for imaging protein-dye conjugates in living cells, J Am Chem Soc, vol.131, pp.1642-1643, 2009.

W. J. Shi, J. Y. Liu, and D. K. Ng, A highly selective colorimetric and fluorescent probe for Cu2+ and Hg2+ ions based on a distyryl BODIPY with two bis(1,2,3-triazole)amino receptors, Chem Asian J, vol.7, pp.196-200, 2012.

S. Madhu, R. Gonnade, and M. Ravikanth, Synthesis of 3,5-bis(acrylaldehyde) boron-dipyrromethene and application in detection of cysteine and homocysteine in living cells, J Org Chem, vol.78, pp.5056-5060, 2013.

P. G. Van-patten, A. P. Shreve, J. S. Lindsey, and R. J. Donohoe, Energy-transfer modeling for the rational design of multiporphyrin light-harvesting arrays, J Phys Chem B, vol.102, pp.4209-4216, 1998.

R. W. Wagner, J. S. Lindsey, J. Seth, V. Palaniappan, and D. F. Bocian, Molecular optoelectronic gates, J Am Chem Soc, vol.118, pp.3996-3997, 1996.

R. K. Lammi, R. W. Wagber, A. Ambroise, J. R. Diers, D. F. Bocian et al., Mechanisms of excited-state energy-transfer gating in linear versus branched multiporphyrin arrays, J Phys Chem B, vol.105, pp.5341-5352, 2001.

T. Yogo, Y. Urano, Y. Ishitsuka, F. Maniwa, and T. Nagano, Highly efficient and photostable photosensitizer based on BODIPY chromophore, J Am Chem Soc, vol.127, pp.12162-12163, 2005.

S. Ozlem and E. U. Akkaya, Thinking outside the silicon box: molecular and logic as an additional layer of selectivity in singlet oxygen generation for photodynamic therapy, J Am Chem Soc, vol.131, pp.48-49, 2009.

S. Kolemen and E. U. Akkaya, Reaction-based BODIPY probes for selective bio-imaging, Coord Chem Rev, vol.354, pp.121-134, 2018.

Y. V. Zatsikha, E. Maligaspe, A. A. Purchel, N. O. Didukh, Y. Wang et al., Tuning electronic structure, redox, and photophysical properties in asymmetric NIR-absorbing organometallic BODIPYs, Inorg Chem, vol.54, pp.7915-7928, 2015.

X. Yin, Y. Li, Y. Li, Y. Zhu, X. Tang et al., Electrochromism based on the charge transfer process in a ferrocene-BODIPY molecule, Tetrahedron, vol.65, pp.8373-8377, 2009.

R. Ziessel, P. Retailleau, K. J. Elliott, and A. Harriman, Boron dipyrrin dyes exhibiting "push-pull-pull" electronic signatures, Chem Eur J, vol.15, pp.10369-10374, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00432411

O. Galangau, I. Fabre-francke, S. Munteanu, C. Dumas-verdes, G. Clavier et al., Electrochromic and electrofluorochromic properties of a new boron dipyrromethene-ferrocene conjugate, Electrochim Acta, vol.87, pp.809-815, 2013.
URL : https://hal.archives-ouvertes.fr/hal-00906515

Y. V. Zatsikha, N. O. Didukh, T. Blesener, M. P. Kayser, Y. P. Kovtun et al., Preparation, characterization, redox, and photoinduced electron-transfer properties of the NIR-absorbing N-ferrocenyl-2-pyridone BODIPYs, Eur J Inorg Chem, pp.318-324, 2017.

M. P. Shandura, V. P. Yakubovskyi, and Y. P. Kovtun, 4-Difluoro-4-bora-3a,4a,-diaza-s-indacen-3-yl)acetaldehyde: synthesis and chemical properties, J Heterocycl Chem, vol.46, issue.4, pp.1386-1391, 2009.

M. R. Rao, K. V. Kumar, and M. Ravikanth, Synthesis of boron-dipyrromethene-ferrocene conjugates, J Organomet Chem, vol.695, pp.863-869, 2010.

X. Yin, Y. Li, Y. Zhu, X. Jing, Y. Li et al., A highly sensitive viscosity probe based on ferrocene-BODIPY dyads, Dalton Trans, vol.39, pp.9929-9935, 2010.

B. Dhokale, P. Gautam, S. M. Mobin, and R. Misra, Donor-acceptor, ferrocenyl substituted BODIPYs with marvelous supramolecular interactions, Dalton Trans, vol.42, pp.1512-1518, 2013.

R. Misra, B. Dhokale, T. Jadhav, and S. M. Mobin, Donor-acceptor meso-alkynylated ferrocenyl BODIPYs: synthesis, structure, and properties, Dalton Trans, vol.42, pp.13658-13666, 2013.

B. Dhokale, T. Jadhav, S. M. Mobin, and R. Misra, Tetracyanobutadiene functionalized ferrocenyl BODIPY dyes, vol.45, 1476.

T. K. Khan, R. R. Pissurlenkar, M. S. Shaikh, and M. Ravikanth, Synthesis and studies of covalently linked meso-furyl boron-dipyrrometheneferrocene conjugates, J Organomet Chem, vol.697, pp.65-73, 2012.

E. Maligaspe, T. J. Pundsack, L. M. Albert, Y. V. Zatsikha, P. V. Solntsev et al., Synthesis and charge-transfer dynamics in a ferrocene-containing organoboryl aza-BODIPY donor-acceptor triad with boron as the hub, Inorg Chem, vol.54, pp.4167-4174, 2015.

C. J. Ziegler, K. Chanawanno, A. Hasheminsasab, Y. V. Zatsikha, E. Maligaspe et al., Synthesis, redox properties, and electronic coupling in the diferrocene aza-dipyrromethene and azaBODIPY donor-acceptor dyad with direct ferrocene??-pyrrole bond, Inorg Chem, vol.53, pp.4751-4755, 2014.

J. L. Jin, S. X. Wu, Y. Geng, S. Y. Yang, G. C. Yang et al., Theoretical study on photophysical properties of novel bis(BF2)-2,2?-bidipyrrins dyes: effect of variation in monomer structure, Int J Quantum Chem, vol.112, pp.440-452, 2012.

R. Sharma, R. Maragani, and R. Misra, Ferrocenyl aza-dipyrromethene and aza-BOD-IPY: synthesis and properties, J Organomet Chem, pp.8-14, 2016.

L. Gao, W. Senevirathna, and G. Sauvé, Azadipyrromethene-based conjugated oligomers with Near-IR absorption and high electron affinity, Org Lett, vol.13, pp.5354-5357, 2011.

Y. V. Zatsikha, C. D. Holstrom, K. Chanawanno, A. J. Osinski, C. J. Ziegler et al., Nemykin, Observation of the strong electronic coupling in Near-infrared-absorbing tetraferrocene aza-dipyrromethene and aza-BODIPY with direct ferrocene-?-and ferrocene??-pyrrole bonds: toward molecular machinery with four-bit information storage capacity, Inorg Chem, vol.56, pp.991-1000, 2017.

N. Balsukuri, S. Mori, and I. Gupta, Donor acceptor type ferrocene substituted aza-BODIPYs: synthesis, optical and electrochemical studies, J Porphyr Phthalocyanines, vol.20, pp.719-729, 2016.

A. Gorman, J. Killoran, C. Shea, T. Kenna, W. M. Gallagher et al., In vitro demonstration of the heavy-atom effect for photodynamic therapy, J Am Chem Soc, vol.126, pp.10619-10631, 2004.

M. J. Hall, S. O. Mcdonnell, J. Killoran, and D. F. O'shea, A modular synthesis of unsymmetrical tetraarylazadipyrromethenes, J Org Chem, vol.70, pp.5571-5578, 2005.

A. Loudet and K. Burgess, BODIPY dyes and their derivatives: Syntheses and spectroscopic properties, Chem Rev, vol.107, pp.4891-4932, 2007.

F. Li, S. I. Yang, T. Ciringh, J. Seth, C. H. Martin et al., Design, synthesis, and photodynamics of light-harvesting arrays comprised of a porphyrin and one, two, or eight boron-dipyrrin accessory pigments, J Am Chem Soc, vol.120, pp.10001-10017, 1998.

M. Tasior and D. F. O'shea, BF2-chelated tetraarylazadipyrromethenes as NIR fluorochromes, Bioconjug Chem, vol.21, pp.1130-1133, 2010.

M. E. El-khouly, S. Fukuzumi, and F. Souza, Photosynthetic antenna-reaction center mimicry by using boron dipyrromethene sensitizers, ChemPhysChem, vol.15, pp.30-47, 2014.

V. N. Nemykin, T. S. Blesener, and C. J. Ziegler, Photophysics, redox processes, and electronic structures of ferrocenyl-containing BODIPYs, aza-BODIPYs, BOPHYs, transition-metal dipyrromethenes and aza-dipyrromethenes, Macroheterocycles, vol.10, pp.9-26, 2017.

A. N. Amin, M. E. El-khouly, N. K. Subbaiyan, M. E. Zandler, M. Supur et al., Syntheses, electrochemistry, and photodynamics of ferrocene-azadipyrromethane donor-acceptor dyads and triads, J Phys Chem A, vol.115, pp.9810-9819, 2011.

V. Bandi, M. E. El-khouly, K. Ohkubo, V. N. Nesterov, M. E. Zandler et al., Bisdonor-azaBODIPY-fullerene supramolecules: syntheses, characterization, and light-induced electron-transfer studies, J Phys Chem C, vol.118, pp.2321-2332, 2014.

V. Bandi, M. E. El-khouly, K. Ohkubo, V. N. Nesterov, M. E. Zandler et al., Excitation-wavelength-dependent, ultrafast photoinduced electron transfer in bisferrocene/BF2-chelated-azadipyrromethene/fullerene tetrads, Chem Eur J, vol.19, pp.7221-7230, 2013.

J. Lenoble, N. Maringa, S. Campidelli, B. Donnio, D. Guillon et al., Liquid-crystalline fullerodendrimers which display columnar phases, Org Lett, vol.8, pp.1851-1854, 2006.
URL : https://hal.archives-ouvertes.fr/hal-00211473

J. Liu, M. E. El-khouly, S. Fukuzumi, and D. K. Ng, Photoinduced electron transfer in a ferrocene-distyryl BODIPY dyad and a ferrocene-distyryl BODIPY-C60 triad, ChemPhysChem, vol.13, pp.2030-2036, 2012.

W. Shi, P. Lo, S. Zhao, R. C. Wong, Q. Wang et al., A biotin-conjugated glutathione-responsive FRET based fluorescent probe with a ferrocenyl BODIPY as the dark quencher, Dalton Trans, vol.45, pp.17798-17806, 2016.

C. A. Wijesinghe, M. E. El-khouly, J. D. Blakemore, M. E. Zandler, S. Fukuumi et al., Charge stabilization in a closely spaced ferrocene-boron dipyrrin-fullerene triad, Chem Commun, vol.46, pp.3301-3303, 2010.

A. Vecchi, P. Galloni, B. Floris, and V. N. Nemykin, New developments in chemistry of organometallic porphyrins and their analogs, J Porphyr Phthalocyanines, vol.17, pp.165-196, 2013.

A. Vecchi, P. Galloni, B. Floris, S. V. Dudkin, and V. N. Nemykin, Metallocenes meet porphyrinoids: consequences of a "fusion, Coord Chem Rev, vol.291, pp.95-171, 2015.

E. Pena-cabrera, A. Aguilar-aguilar, M. Gonzalez-domingues, E. Lager, R. Zamudio-vazquez et al., Simple, general, and efficient synthesis of meso-substituted borondipyrromethenes from a single platform, Org Lett, vol.9, pp.3985-3988, 2007.

P. Gautam, B. Dhokale, S. M. Mobin, and R. Misra, Ferrocenyl BODIPYs: synthesis, structure and properties, RSC Adv, vol.2, pp.12105-12107, 2012.

R. Ziessel, P. Retailleau, K. J. Elliott, and A. Harriman, Boron dipyrrin dyes exhibiting "push-pull-pull" electronic signatures, Chem Eur J, vol.15, pp.10369-10374, 2009.
URL : https://hal.archives-ouvertes.fr/hal-00432411

R. Misra, B. Dhokale, T. Jadhav, and S. M. Mobin, Heteroatom-connected ferrocenyl BODIPYs: synthesis, structure, and properties, vol.33, pp.1867-1877, 2014.

N. O. Didukh, Y. V. Zatsikha, G. T. Rohde, T. S. Blesener, V. P. Yakubovskyi et al., NIR absorbing diferrocene-containing meso-cyano-BOD-IPY with a UV-Vis-NIR spectrum remarkably close to that of magnesium tetracyanotetraferrocenyltetraazaporphyrin, Chem Commun, vol.52, pp.11563-11566, 2016.

A. Treibs, F. Kreuzer, and . Difluorboryl-komplexe-von-di-und-tripyrrylmethenen, Liebigs Ann Chem, vol.718, pp.208-223, 1968.

J. H. Boyer, A. M. Haag, G. Sathyamoorthi, M. Soong, K. Thangaraj et al., Pavlopoulos, Pyrromethene-BF 2 complexes as laser dyes: 2, Heteroat Chem, vol.1, pp.39-49, 1993.

,

G. Sathyamoorthi, J. H. Boyer, T. H. Allik, and S. Chandra, Laser active cyanopyrromethene-BF2 complexes, Heteroat Chem, vol.5, pp.403-407, 1994.

S. Kim, J. Bouffard, and Y. Kim, Tailoring the solid-state fluorescence emission of BODIPY dyes by meso substitution, Chem Eur J, vol.21, pp.17459-17465, 2015.

V. P. Yakubovskyi, N. O. Didukh, Y. V. Zatsikha, and Y. P. Kovtun, A new approach to the synthesis of meso-CN-substituted BODIPYs, Chemistry, vol.1, pp.1462-1466, 2016.

Y. V. Zatsikha, N. O. Didukh, D. Nemez, A. C. Schlachter, P. Karsenti et al., Ferrocene-BODIPY merocyanine dyads: new NIR absorbing platforms with optical properties susceptible to protonation, Chem Commun, vol.53, pp.7612-7615, 2017.

V. P. Yakubovskyi, M. P. Shandura, Y. P. Kovtun, and . Boradipyrromethenecyanines, Eur J Org Chem, pp.3237-3243, 2009.

V. P. Yakubovskyi, M. P. Shandura, and Y. P. Kovtun, Boradipyrromethenecyanines derived from conformationally restricted nuclei, Dyes Pigments, vol.87, pp.17-21, 2010.

M. P. Shandura, V. P. Yakubovskyi, A. O. Gerasov, O. D. Kachkovsky, Y. M. Poronik et al., ?-Polymethine-substituted boron dipyrromethenes-BODIPY-based NIR cyanine-like dyes, Eur J Org Chem, pp.1825-1834, 2012.

M. P. Shandura, V. P. Yakubovskyi, and Y. P. Kovtun, (acetaldehyde) substituted BODIPY, Org Biomol Chem, vol.3, pp.835-841, 2011.

M. P. Shandura, V. P. Yakubovskyi, Y. V. Zatsikha, O. D. Kachkovsky, Y. M. Poronik et al., Anionic, cationic and merocyanine polymethine dyes based on dipyrromethene core, Dyes Pigments, vol.98, pp.113-118, 2013.

Y. V. Zatsikha, V. P. Yakubovskyi, M. P. Shandura, and Y. P. Kovtun, Boradipyrromethenecyanines on the base of a BODIPY nucleus annelated with a pyridone ring: a new approach to long-wavelength dual fluorescent probe design, RSC Adv, vol.3, pp.24193-24201, 2013.

V. P. Yakubovskyi, Y. V. Zatsikha, M. P. Shandura, and Y. P. Kovtun, Boradipyrromethenecyanines of different electronic symmetry: a demonstration of the potential of BODIPY nucleus as end group in polymethine chromophoric system, Dyes Pigments, vol.106, pp.161-167, 2014.

Y. V. Zatsikha, T. S. Blesener, P. C. Goff, A. T. Healy, R. K. Swedin et al., -Dipyrene-containing aza-BODIPYs: are pyrene groups effective as ligands to promote and direct complex formation with common nanocarbon materials?, J Phys Chem C, vol.1, issue.7, pp.27893-27916, 2018.

H. M. Rhoda, K. Chanawanno, A. J. King, Y. V. Zatsikha, C. J. Ziegler et al., Unusually strong long-distance metal-metal coupling in bis(ferrocene)-containing BOPHY: an introduction to organometallic BOPHYs, Chem Eur J, vol.21, pp.18043-18046, 2015.

I. Tamgho, A. Hasheminasab, J. T. Engle, V. N. Nemykin, and C. J. Ziegler, A new highly fluorescent and symmetric pyrrole-BF2 chromophore: BOPHY, J Am Chem Soc, vol.136, pp.5623-5626, 2014.

D. Delmarre, R. Méallet, C. Bied-charreton, and R. B. Pansu, Heavy metal ions detection in solution, in sol-gel and with grafted porphyrin monolayers, J Photochem Photobiol A Chem, vol.124, pp.46-51, 1999.

Y. Ding, W. Zhu, and Y. Xie, Development of ion chemosensors based on porphyrin analogues, Chem Rev, vol.117, pp.2203-2256, 2017.

A. K. Burrell, W. M. Campbell, G. B. Jameson, D. L. Officer, P. D. Boyd et al., Bis(ferrocenyl)porphyrins. Compounds with strong long-range metal-metal coupling, Chem Commun, pp.637-638, 1999.

S. J. Narayanan, S. Venkatraman, S. R. Dey, B. Sridevi, V. G. Anand et al., Synthesis of meso ferrocenyl porphyrins, pp.1834-1836, 2000.

J. Rochford, A. D. Rooney, and M. T. Pryce, Redox control of meso-zinc(II) ferrocenylporphyrin based fluorescence switches, Inorg Chem, vol.46, pp.7247-7249, 2007.

D. T. Gryko, F. Zhao, A. A. Yasseri, K. M. Roth, D. F. Bocian et al., Synthesis of thiol-derivatized ferrocene-porphyrins for studies of multibit information storage, J Org Chem, vol.65, pp.7356-7362, 2000.

A. K. Burrell, W. M. Campbell, D. L. Officer, S. M. Scott, K. C. Gordon et al., McDonald, Synthesis, reactivity and spectroscopy of ferrocene-functionalized porphyrins, with a conjugated connection between the ferrocene and the porphyrin core, J Chem Soc Dalton Trans, pp.3349-3354, 1999.

V. N. Nemykin, E. A. Makarova, J. O. Grosland, S. V. Dudkin, R. Dennison et al., Tuning the near-IR band energy and redox potentials of magnesium tetra(ferrocenyl)tetraazaporphyrins, J Porphyr Phthalocyanines, vol.18, pp.792-803, 2014.

V. N. Nemykin, A. Y. Maximov, and A. Y. Koposov, Mercury-free preparation, characterization, and molecular structure of tricyanovinylferrocene using an unusual reaction between ferrocene and tetracyanoethylene, Organometallics, vol.26, pp.3138-3148, 2007.

V. N. Nemykin, E. A. Makarova, J. O. Grosland, R. G. Hadt, and A. Y. Koposov, Preparation, characterization, molecular and electronic structures, TDDFT, and TDDFT/ PCM study of the solvatochromism in cyanovinylferrocenes, Inorg Chem, vol.46, pp.9591-9601, 2007.

S. Rai, G. Gayatri, G. Sastry, and M. Ravikanth, Effects of meso-substituents and core-modification on photophysical and electrochemical properties of porphyrin-ferrocene conjugates, Chem Phys Lett, vol.467, pp.179-185, 2008.

I. Gupta and M. Ravikanth, Synthesis of meso-furyl porphyrins with N4, N3S, N2S2 and N3O porphyrin cores, Tetrahedron, vol.59, pp.950-955, 2003.

L. L. Grazynski, J. Lisowski, M. M. Olmstead, and A. L. Balch, 21-Thiatetra-p-tolylporphyrin and its copper(II) bicarbonate complex. Structural effects of copper-thiophene binding, J Am Chem Soc, vol.109, pp.4428-4429, 1987.

A. Ulman and J. Manassen, Synthesis of new tetraphenylporphyrin molecules containing heteroatoms other than nitrogen. I. Tetraphenyl-21,23-dithiaporphyrin, J Am Chem Soc, vol.97, pp.6540-6544, 1975.

A. Treibs and K. Jacob, Cyclotrimethine dyes derived from squaric acid, Angew Chem, Int Ed Engl, vol.4, pp.694-694, 1965.

L. Hu, Z. Yan, and H. Xu, Advances in synthesis and application of near-infrared absorbing squaraine dyes, RSC Adv, vol.3, pp.7667-7676, 2013.

H. Meier and R. Petermann, Near infrared dyes by combination of squaraine and ferrocene chromophores, Tetrahedron Lett, vol.41, pp.892-895, 2000.

Y. W. Huang and N. Y. Fu, Synthesis and properties of a novel squaraine dye modified by ferrocene, Chin Chem Lett, vol.22, pp.1301-1304, 2011.

M. C. Aragoni, M. Arca, F. Demartin-;-m-=-ni, . Pd, ;. Pt et al., timdt = monoanion of disubstituted imidazolidine-2,4,5-trithiones): an experimental and theoretical investigation, New [M(R,R'timdt)2] metal-dithiolenes and related compounds, vol.121, pp.7098-7107, 1999.

P. Chandrasekaran, A. F. Greene, K. Lillich, S. Capone, J. T. Mague et al., A structural and spectroscopic investigation of octahedral platinum bis(dithiolene)phosphine complexes: platinum dithiolene internal redox chemistry induced by phosphine association, Inorg Chem, vol.53, pp.9192-9205, 2014.

S. Dalgleish, M. M. Matsushita, L. G. Hu, B. Li, H. Yoshikawa et al., Utilizing photocurrent transients for dithiolene-based photodetection: stepwise improvements at communications relevant wavelengths, J Am Chem Soc, vol.134, pp.12742-12750, 2012.

G. Bruno, M. Almeida, F. Artizzu, J. C. Dias, M. L. Mercuri et al., Innocence and noninnocence of the ligands in bis(pyrazine-2,3-dithiolate and -diselonate) d8-metal complexes. A theoretical D. Brunel et al. Dyes and Pigments xxx (xxxx) xxx-xxx and experimental study for the Cu(III), Au(III) and Ni(II) cases, Dalton Trans, vol.39, pp.4566-4574, 2010.

R. Perochon, P. Davidson, S. Rouzière, F. Camerel, L. Piekara-sady et al., Probing magnetic interactions in columnar phases of a paramagnetic gold dithiolene complex, J Mater Chem, vol.21, pp.1416-1422, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00601702

S. Dalgleish and N. Robertson, A stable near IR switchable electrochromic polymer based on an indole-substituted nickel dithiolene, Chem Commun, vol.39, pp.5826-5828, 2009.

S. Oliveira, M. L. Afonso, S. I. Dias, I. C. Santos, R. T. Henriques et al., An electropolymerisable pyridine-functionalised gold bis(dithiolene) complex, Eur J Inorg Chem, vol.18, pp.3133-3136, 2013.

D. Espa, L. Marchiò, L. Pilia, M. L. Mercuri, F. Artizzu et al., Mixed-ligand Pt(II) dithione-dithiolato complexes: influence of the dicyanobenzodithiolato ligand on the second-order NLO properties, Dalton Trans, vol.41, pp.3485-3493, 2012.

X. Chen, W. Qiao, B. Liu, J. Ren, and Z. Wang, Synthesis and near infrared electrochromic properties of metallodithiolene complexes, Sci China Chem, vol.60, pp.1-7, 2017.

B. Liu, W. Qiao, and Z. Y. Wang, Colorless metallodithiolene oligomers and polymers with intense near-and mid-infrared absorption, RSC Adv, vol.5, pp.6815-6822, 2015.

S. B. Wilkes, I. R. Butler, A. E. Underhill, A. Kobayashi, and H. Kobayashi, Synthesis of the first diferrocenyl-dithiolene metal complex: bis(ferrocenylethy1ene-12-dithiolato)nickelate(ii), J Chem Soc, Chem Commun, pp.53-54, 1994.

U. T. Mueller-westerhoff, D. I. Yoon, and K. Plourde, Near-ir dyes for the 1.3 to 1.5 micron region: the use of substituted dithiolene complexes, Mol Cryst Liq Cryst, vol.183, pp.291-302, 1990.

S. B. Wilkes, I. R. Butler, A. E. Underhill, M. B. Hursthouse, D. E. Hibbs et al., Malik, Synthesis, crystal structure and properties of novel ferrocenyl multisulfur compounds, J Chem Soc Dalton Trans, pp.897-903, 1995.

H. Lee and D. Noh, Syntheses, X-ray crystal structures and properties of di-and tetraferrocenyl nickel-bis(1,4-dithiin-5,6-dithiolate) complexes, J Mater Chem, vol.10, pp.2167-2172, 2000.

U. T. Mueller-westerhoff and R. W. Sanders, Electronic spectra of ferrocenyl-dithiolene nickel complexes: steric and electron donor/acceptor effects, Organometallics, vol.22, pp.4778-4782, 2003.

S. B. Wilkes, I. R. Butler, A. E. Underhill, A. Kobayashi, and H. Kobayashi, Synthesis of the first diferrocenyl-dithiolene metal complex: bis(ferrocenylethylene-1,2-dithiolato) nickelate(II), J Chem Soc, Chem Commun, pp.53-54, 1994.

A. E. Underhill, A. Charlton, S. B. Wilkes, I. R. Butler, A. Kobayashi et al., Developments in the chemistry of sulphur-donor ligands, Synth Met, vol.70, pp.1101-1104, 1995.

H. J. Lee, N. Dong-youn, and . Syntheses, X-ray crystal structures and properties of diand tetra-ferrocenyl nickel-bis(1,4-dithiin-5,6-dithiolate)complexes, J Mater Chem, vol.10, pp.2167-2172, 2000.

T. Kusamoto, K. Takada, R. Sakamoto, S. Kume, and H. Nishihara, Ferrocene-dithiolene hybrids: control of strong donor?acceptor electronic communication to reverse the charge transfer direction, Inorg Chem, vol.51, pp.12102-12113, 2012.

S. R. Marder, J. W. Perry, and B. G. Tiemann, Organometallic salts with large second-harmonic-generation powder efficiencies: (E)-1-ferrocenyl-2-(1-methyl-4-pyridiniumyl)ethylene salts, Organometallics, vol.10, pp.1896-1901, 1991.

V. Alain, M. Blanchard-desce, C. Chen, S. R. Marder, A. Fort et al., Large optical nonlinearities with conjugated ferrocene and ruthenocene derivatives, Synth Met, vol.81, issue.96, pp.3743-3748, 1996.

C. Lambert, W. Gaschler, M. Zabel, R. Matschiner, and R. Wortmann, Linear and non-linear optical properties of arene-Fe-Cp complexes, J Organomet Chem, vol.592, pp.109-114, 1999.

T. Müller, A. Netz, and M. Ansorge, Syntheses and NLO properties of chromium carbonyl arene complexes with conjugated side chains: the amphoteric nature of chromium carbonyl complexation in push-pull chromophores, Organometallics, vol.18, pp.5066-5074, 1999.

H. Wong, T. Meyer-friedrichsen, T. Farrell, C. Mecker, and J. Heck, Second harmonic generation and two-photon fluorescence as nonlinear optical properties of dipolar mononuclear sesquifulvalene complexes, Eur J Inorg Chem, pp.631-646, 2000.

I. R. Whitall, A. M. Mcdonagh, and M. G. Humphrey, Organometallic complexes in nonlinear optics I: second-order nonlinearities, Adv Organomet Chem, vol.42, pp.60545-60551, 1998.

M. B. Hall and R. F. Fenske, Electronic structure and bonding in methyl-and perfluoromethyl (pentacarbonyl)manganese, Inorg Chem, vol.11, pp.768-775, 1972.

C. P. Casey, M. S. Konings, S. R. Marder, and Y. Takezawa, Diiron ?-vinylcarbyne complexes have unusually low barriers to vinyl rotation because conjugation is main tained throughout rotation, J Organomet Chem, vol.358, p.87089, 1988.

C. P. Casey, M. S. Konings, and S. R. Marder, Synthesis of cationic diiron ?-vinylcarbyne complexes, Polyhedron, vol.7, issue.00, p.86310, 1988.

C. P. Casey, M. S. Konings, and S. R. Marder, Addition of nucleophiles to cationic diiron ?-vinylcarbyne complexes; synthesis of functionalized diiron ?-alkenylidene complexes, J Organomet Chem, vol.345, pp.80241-80250, 1988.

J. A. Bandy, H. E. Bunting, M. Garcia, M. L. Green, S. R. Marder et al., Thompson, Second-order non-linear optical properties of diironalkenylidyne complexes; crystal structure of {(?-C5H5)2Fe2(CO)2(?-CO)(?-(E)C-CH=CH-C6H4-(p)-NMe2)}+BF4?, Polyhedron, vol.12, pp.83135-83141, 1992.

T. Farrell, T. Meyer-friedrichsen, J. Heck, and A. R. Manning, Linear and nonlinear optical properties of diiron ?-vinylcarbyne acceptor and stilbenyl donor based chromophores, Organometallics, vol.19, pp.3410-3419, 2000.

T. Farrell, A. R. Manning, T. C. Murphy, T. Meyer-friedrichsen, J. Heck et al., Asselberghs, A. Persoons, Structure-property dependence of the first hyperpolarisabilities of organometallic merocyanines based on the ì-vinylcarbynediiron acceptor and ferrocene donor, Eur J Inorg Chem, pp.2365-2375, 2001.

C. Reichardt, Solvents and solvent effects in organic chemistry, 1988.

A. K. -y.-jen, V. Rao, K. Y. Wong, and K. J. Drost, Functionalized thiophenes: second-order nonlinear optical materials, J Chem Soc, Chem Commun, pp.90-92, 1993.

V. Rao, A. K. .-y.-jen, K. Y. Wong, and K. J. Drost, Dramatically enhanced second-order nonlinear optical susceptibilities in tricyanovinylthiophene derivatives, J Chem Soc, Chem Commun, pp.1118-1120, 1993.

A. K. -y.-jen, Y. Cai, P. V. Bedworth, and S. R. Marder, Synthesis and characterization of highly efficient and thermally stable diphenylamino-substituted thiophene stilbene chromophores for nonlinear optical applications, Adv Mater, vol.9, pp.132-135, 1997.

G. A. Razuvaev, G. A. Domrachev, V. V. Sharutin, and O. N. Suvorova, Ferrocenyl derivatives of dicyclopentadienyl-titanium, -zirconium and -hafnium, J Organomet Chem, vol.141, pp.313-317, 1977.

M. Wedler, H. W. Roesky, and F. T. Edelmann, Behrens UT-ferrocenyl-komplexe der frühen ubergangsmetalle-synthese und struktur, Z Naturforsch B Chem Sci, vol.43, pp.1461-1467, 1988.

H. Gornitzka, F. T. Edelmann, and K. Jacob, Ferrocenhaltige liganden in der lanthanid-chemie: alkoxide und thiolate, J Organomet Chem, vol.436, pp.325-332, 1992.

S. Köcher, B. Walfort, G. Rheinwald, T. Rüffer, and H. Lang, Alkyloxy-and aryloxy-titanocenes: synthesis, solid-state structure and cyclic voltammetric studies, J Organomet Chem, vol.693, pp.3213-3222, 2008.

P. Song, L. Liu, C. Han, and Q. Hu, Synthesis and characterization of Cp2Ti-containing organometallics via in situ oxidative-addition of 'Cp2Ti' intermediate.: crystal structures of (1-C10H7S)2TiCp2, [(?5-C5H5)Fe(?5-C5H4CH2S)]2TiCp2 and [?2-OC(Ph)-C(ph)O]TiCp2, J Organomet Chem, vol.648, pp.1413-1422, 2002.

H. Muraoka, S. Ogawa, N. Nagahora, Y. Kawai, and R. Sato, Synthesis of new pentathiepin and dithiatriselenepin fused to ferrocene via dithiametallacycles, Bull Chem Soc Jpn, vol.78, pp.2026-2036, 2005.

R. Steudel, K. Hassenberg, J. Pickardt, E. Grigiotti, and P. Zanello, Synthetic and electrochemical studies on 1,1'-dithia-substituted derivatives of ferrocene and structure of, Organometallics, vol.1, pp.2604-2608, 2002.

B. Gautheron and G. Tainturier, Conformation de metalladiselenaferocenophanes Fe(?5-C5H4Se)2M(?5-C5H4R)2 (M = Zr, Hf), vol.262, pp.99169-99170, 1984.

R. Broussier, Y. Gobet, R. Amardeil, A. Da-rold, M. M. Kubicki et al., Un nouveau type de ferrocénophane, premier exemple de structure dimère, J Organomet Chem, vol.445, issue.93, p.80221, 1993.

P. Frenzel, M. Korb, A. Hildebrandt, and H. Lang, Synthesis and electrochemical behavior of ferrocenyl-functionalized metallocenes M(?5-C5H5), vol.2

E. , S. Se, and ). , Eur J Inorg Chem, vol.27, pp.3143-3143, 2018.

G. Noirbent and F. Dumur, Recent advances on nitrofluorene derivatives: versatile electron acceptors to create dyes absorbing from the visible to the near and far infrared region, Materials, vol.11, 2018.
URL : https://hal.archives-ouvertes.fr/hal-02091875

I. F. Perepichka, D. F. Perepichka, M. R. Bryce, A. Chesne, A. F. Popov et al., Push-pull fluorene acceptors with ferrocene donor moiety, Synth Met, vol.102, pp.563-566, 1999.

D. F. Perepichka, I. F. Perepichka, A. F. Popov, M. R. Bryce, A. S. Batsanov et al., Electron acceptors of the fluorene series, Metalloceneylidene)nitrofluorene derivatives of Fc-NF, NF-Fc-NF, and NF-Rc-NF types, and the vinylogues Fc--NF: synthesis, characterisation, intramolecular charge transfer, redox properties and X-ray structures for three fluo, vol.12

D. Brunel, Dyes and Pigments xxx (xxxx) xxx-xxx rene-ferrocene derivatives, J Organomet Chem, pp.445-462, 2001.