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Synthesis, characterization and modeling of self-assembled porphyrin nanorods

Abstract : Porphyrin nanorods were prepared by ion-association between free-base meso 5,10,15,20-tetrakis-(4-N-methylpyridinium)porphyrin cations and tetraphenylborate anions. The nanorods have variable lengths (up to a few micrometers long) and diameters (∼50–500 nm). Their structure at the molecular level was elucidated by combining multinuclear solid state NMR spectroscopy, synchrotron X-ray powder diffraction and DFT calculations.
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Danielle Laurencin, Pascal Yot, Christel Gervais, Yannick Guari, Sébastien Clément, et al.. Synthesis, characterization and modeling of self-assembled porphyrin nanorods. Journal of Porphyrins and Phthalocyanines, World Scientific Publishing, 2019, 2019 Women in Porphyrin Science, 23 (11n12), pp.1346-1354. ⟨10.1142/S1088424619501451⟩. ⟨hal-02454505⟩

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