Investigation of new modification strategies for PVA membranes to improve their dehydration properties by pervaporation

M E Dmitrenko (1) , A. V. Penkova (1) , A. I. Kuzminova (1) , M Mahbub (2) , M. I. Larionov (1) , Halima Alem (3) , A. A. Zolotarev (1) , S S Ermakov (1) , D. Roizard (2)

1 SPbU - St Petersburg State University
2 LRGP - Laboratoire Réactions et Génie des Procédés
3 IJL - Institut Jean Lamour

Novel supported membranes based on polyvinyl alcohol (PVA) were developed using two strategies: first, by the modification of the PVA network, via so-called bulk modification, with the formation of the selective layer accomplished through the introduction of fullerenol and/or poly(allylamine hydrochloride), and second, by the functionalization of the surface with successive depositions of multilayered films of polyelectrolytes, such as poly(allylamine hydrochloride) and poly(sodium 4-styrenesulfonate) on the PVA surface. The membrane surface modifications were characterized by scanning electron microscopy and contact angle measurements. The modified PVA membranes were examined for their dehydration transport properties by the perva-poration of isopropyl alcohol-water (80/20% w/w), which was chosen as a model mixture. Compared with the pristine PVA membrane, the main improvement was a marked increase in permeance. It was found that the surface modifications mainly gave rise to a higher global flux but with a strong reduction in selectivity. Only the combination of both bulk and surface modifications with PEL could significantly increase the flux with a high water content in the permeate (over 98%). Lastly, it should be noted that this study developed a green procedure to prepare innovative membrane layers for dehydration, making use of only water as a working medium.

Domaines: Génie chimique; Polymères

M E Dmitrenko, A. V. Penkova, A. I. Kuzminova, M Mahbub, M. I. Larionov, et al.. Investigation of new modification strategies for PVA membranes to improve their dehydration properties by pervaporation. Applied Surface Science, 2018, 450, pp.527-537. ⟨10.1016/j.apsusc.2018.04.169⟩. ⟨hal-02391697⟩