F. Jin, X. Li, and S. Park, Synthesis and application of epoxy resins: A review, J. Ind. Eng. Chem, vol.29, pp.1-11, 2015.

C. Wang, J. R. Berman, L. L. Walker, and A. Menzona, Meta-bromobiphenol epoxy resins: Applications in electronic packaging and printed circuit board, J. Appl. Polym. Sci, vol.43, pp.1315-1321, 1991.

J. Lo and E. Pearce, Flame-retardant epoxy resins based on phthalide derivative, J. Polym. Sci. Polym. Chem. Ed, vol.22, pp.1707-1715, 1984.

S. D. Shaw, A. Blum, R. Weber, K. Kannan, D. Rich et al., Halogenated flame retardants: Do the fire safety benefits justify the risks?, Rev. Environ. Health, vol.25, pp.261-305, 2010.

Y. Ecochard, M. Decostanzi, C. Negrell, and R. Sonnier, Cardanol and eugenol based flame retardant epoxy monomers for thermostable networks, Molecules, vol.24, 1818.
URL : https://hal.archives-ouvertes.fr/hal-02127053

R. Ménard, C. Negrell, M. Fache, L. Ferry, R. Sonnier et al., From a bio-based phosphorus-containing epoxy monomer to fully bio-based flame-retardant thermosets, RSC Adv, vol.5, pp.70856-70867, 2015.

R. Sonnier, A. Taguet, L. Ferry, and J. Lopez-cuesta, Toward Bio-Based Flame Retardant Polymers, 2017.

A. Pizzi, Chapter 8-Tannins: Major Sourced, Properties and Applications, Monomers, pp.179-199, 2008.

K. Khanbabaee, T. Ree, and . Van-tannins, Classification and Definition, Nat. Prod. Rep, vol.18, pp.641-649, 2001.

G. Tondi, S. Wieland, T. Wimmer, M. F. Thevenon, A. Pizzi et al., Tannin-boron preservatives for wood buildings: Mechanical and fire properties, Eur. J. Wood Wood Prod, vol.70, pp.689-696, 2012.

G. Tondi, L. Haurie, S. Wieland, A. Petutshnigg, A. Lacasta et al., Comparison of disocium octaborate tetrahydrate-based and tannin-boron-based formulations as fire retardant for wood structures, Fire Mater, vol.38, pp.381-390, 2014.

T. Yang, J. Guan, R. Tang, and G. Chen, Condensed tannin from Dioscorea cirrhosa tuber as an eco-friendly and durable flame retardant for silk textile, Ind. Crops Prod, vol.115, pp.16-25, 2018.

S. Nam, B. D. Condon, Z. Xia, R. Nagarajan, D. J. Hinchliffe et al., Intumescent flame-retardant cotton produced by tannic acid and sodium hydroxide, J. Anal. Appl. Pyrolysis, vol.126, pp.239-246, 2017.

F. Laoutid, V. Karaseva, L. Costes, S. Brohez, and R. Mincheva, Novel bio-based flame retardant systems derived from tannic acid, J. Renew. Mater, vol.6, pp.559-572, 2018.

A. Aguilera-carbo, C. Augur, L. A. Prado-barragan, E. Favela-torres, and C. N. Aguilar, Microbial production of ellagic acid and biodegradation of ellagitannins, Appl. Microbiol. Biotechnol, vol.78, pp.189-199, 2008.

B. A. Howell, K. L. Oberdorfer, and E. A. Ostrander, Phosphorus flame retardants for polymeric materials from gallic acid and other naturally occurring multihydroxybenzoic acids, Int. J. Polym. Sci, 2018.

K. K. Shen, R. O'connor, . Flame, and . Retardants, Borates. In Plastics Additives: An A-Z Reference

G. Pritchard, . Ed, &. Chapman, and . Hall, , 1998.

S. D. Jadhav, A review of non-halogenated flame retardant, Pharma Innov. J, vol.7, pp.380-386, 2018.

K. K. Shen, Chapter 6-Boron-based flame retardants in non-halogen-based polymers, In Polymer Green Flame Retardants, pp.201-241, 2014.

K. K. Shen, Chapter 11-Review of recent advances on the use of boron-based Flame Retardants, pp.367-388, 2014.

P. M. Visakh, O. B. Nazarenko, Y. A. Amelkovich, and T. Melnikova, V Thermal properties of epoxy composites filled with boric acid, Mater. Sci. Eng. R Reports, vol.81, pp.1-6, 2015.

K. Yamada, Chapter 8-A solid-state NMR study of boric acid doped in poly (vinyl alcohol), NMR Spectroscopy of Polymers: Innovative Strategies for Complex Macromolecules; Series, A.S, pp.133-146, 2011.

S. Moldoveanu and . Chapter, Analytical pyrolysis of natural organic polymers. In Techniques and Instrumentation in Analytic Chemistry, pp.217-315, 1998.

C. R. Rao, V. B. Reddy, and P. N. Mehrotra, Derivatographic studies of gallic acid, Thermochim. Acta, vol.46, pp.65-69, 1981.

D. J. Coleman and G. Pilcher, Heats of combustion of biphenyl, bibenzyl, naphthalene, anthracene and phenanthrene, Trans. Faraday Soc, vol.62, pp.821-827, 1966.

W. J. Bailey and C. N. Bird, Pyrolysis of Esters. 27. Pyrolysis of Lactones, J. Org. Chem, vol.42, pp.3895-3899, 1977.

R. F. Brown, Pyrolytic methods in organic chemistry: Application of flow and flash vacuum pyrolytic techniques, 1980.

G. C. Galletti and P. Bocchini, Behaviour of catechin and ellagic acid subjected to therrnally-assisted hydrolysis -methylation/gas chrornatography/mass spectrometry, Rapid Commun. Mass Spectrom, vol.9, pp.250-254, 1995.

N. N. Greenwood, Chemistry of the Elements, pp.139-215, 1984.

G. Dorez, L. Ferry, R. Sonnier, A. Taguet, and J. M. Lopez-cuesta, Effect of cellulose, hemicellulose and lignin contents on pyrolysis and combustion of natural fibers, J. Anal. Appl. Pyrolysis, vol.107, pp.323-331, 2014.

G. Pritchard, Plastics Additives: An A-Z Reference, vol.9401158622, 1997.

G. Whitaker and R. T. Ltd, Overview of the technical compounder, Proceedings of the Enhancing Polymers Using Additives and Modifiers, p.49, 1996.

J. Galy, A. Sabra, and J. Pascault, Characterization of epoxy thermosetting systems by differential scanning calorimetry, Polym. Eng. Sci, vol.26, pp.1514-1523, 1986.

M. P. Pham, Theoretical Studies of Mechanisms of Epoxy Curing Systems, 2011.

L. Costes, F. Laoutid, S. Brohez, C. Delvosalle, and P. Dubois, Phytic acid-lignin combination: A simple and efficient route for enhancing thermal and flame retardant properties of polylactide, Eur. Polym. J, vol.94, pp.270-285, 2017.

P. Müller, M. Morys, A. Sut, B. Illerhaus, J. Christian et al., Melamine poly (zinc phosphate) as fl ame retardant in epoxy resin: Decomposition pathways, molecular mechanisms and morphology of fire residues, Polym. Degrad. Stab, vol.130, pp.307-319, 2016.

B. Schartel and M. Patrick, Melamine poly (metal phosphates) as flame retardant in epoxy resin: Performance, modes of action and synergy, J. Appl. Polym. Sci, vol.133, pp.1-14, 2016.

B. Schartel and T. R. Hull, Development of fire-retarded materials -Interpretation of cone calorimeter data. Fire Mater, vol.31, pp.327-354, 2007.

R. Sonnier, L. Ferry, C. Longuet, F. Laoutid, and B. Friederich, Combining cone calorimeter and PCFC to determine the mode of action of flame-retardant additives, Polym. Adv. Technol, vol.22, pp.1091-1099, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00649884

I. A. Khan and D. Sen, Studies on the complex formation of boron with aromatic hydroxy compounds, Indian Acad. Sci, vol.49, pp.226-233, 1958.

C. Huggett, Estimation of rate of heat release by means of oxygen consumption measurements, Fire Mater, vol.4, pp.61-65, 1980.

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