Homogeneous sulfur isotope signature in East Antarctica and implication for sulfur source shifts through the last glacial-interglacial cycle

Sakiko Ishino (1) , Shohei Hattori (1) , Joel Savarino (2) , Michel Legrand (3) , Emmanuelle Albalat (4) , Francis Albarède (5) , Susanne Preunkert (6) , Bruno Jourdain (6) , Naohiro Yoshida

1 School of Materials and Chemical Technology, Tokyo Institute of Technology, 226‐8502 Yokohama, Japan
2 UGA [2016-2019] - Université Grenoble Alpes [2016-2019]
3 LOA - Laboratoire d’Optique Atmosphérique - UMR 8518
4 LGL-TPE - Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement
5 LST - Laboratoire de Sciences de la Terre
6 IGE - Institut des Géosciences de l’Environnement

Sulfate aerosol (So 4 2−) preserved in Antarctic ice cores is discussed in the light of interactions between marine biological activity and climate since it is mainly sourced from biogenic emissions from the surface ocean and scatters solar radiation during traveling in the atmosphere. However, there has been a paradox between the ice core record and the marine sediment record; the former shows constant nonsea-salt (nss-) So 4 2− flux throughout the glacial-interglacial changes, and the latter shows a decrease in biogenic productivity during glacial periods compared to interglacial periods. Here, by ensuring the homogeneity of sulfur isotopic compositions of atmospheric nss-So 4 2− (δ 34 S nss) over East Antarctica, we established the applicability of the signature as a robust tool for distinguishing marine biogenic and nonmarine biogenic So 4 2−. Our findings, in conjunction with existing records of nss-SO 4 2− flux and δ 34 S nss in Antarctic ice cores, provide an estimate of the relative importance of marine biogenic So 4 2− during the last glacial period to be 48 ± 10% of nss-SO 4 2− , slightly lower than 59 ± 11% during the interglacial periods. Thus, our results tend to reconcile the ice core and sediment records, with both suggesting the decrease in marine productivity around Southern ocean under the cold climate.

Domaines: Océan, Atmosphère

Sakiko Ishino, Shohei Hattori, Joel Savarino, Michel Legrand, Emmanuelle Albalat, et al.. Homogeneous sulfur isotope signature in East Antarctica and implication for sulfur source shifts through the last glacial-interglacial cycle. Scientific Reports, 2019, 9 (1), ⟨10.1038/s41598-019-48801-1⟩. ⟨hal-02350372⟩