V. K. Sreenivasan, A. V. Zvyagin, and E. M. Goldys, J. Phys.: Condens. Matter, vol.25, pp.194101-194124, 2013.

J. Li and J. Zhu, Analyst, vol.138, pp.2506-2515, 2013.

C. Fu, H. Lee, K. Chen, T. Lim, H. Wu et al., Proc. Natl. Acad. Sci. U. S. A, vol.104, issue.3, pp.727-732, 2007.

Y. Yeh, B. Creran, and V. M. Rotello, Nanoscale, vol.4, pp.1871-1880, 2012.

F. Wang, W. B. Tan, Y. Zhang, X. P. Fan, and M. Q. Wang, Nanotechnology, vol.17, pp.1-13, 2006.

F. Oltolina, L. Gregoletto, D. Colangelo, J. Gómez-morales, J. M. Delgado-lópez et al., Langmuir, vol.31, pp.1766-1775, 2015.

T. S. Perera, Y. Han, X. Lu, X. Wang, H. Dai et al., J. Nanomater, p.6, 2015.

A. Al-kattan, V. Santran, P. Dufour, J. J. Dexpert-ghys, and C. Drouet, J. Biomater. Appl, vol.28, pp.697-707, 2014.

A. Al-kattan, P. Dufour, J. Dexpert-ghys, and C. Drouet, J. Phys. Chem. C, vol.114, pp.2918-2924, 2010.

S. Ranjbarvaziri, S. Kiani, A. Akhlaghi, A. Vosough, H. Baharvand et al., Biomaterials, vol.32, pp.5195-5205, 2011.

A. Al-kattan, S. Girod-fullan, C. Charvillat, H. Ternet-fontebasso, P. Dufour et al., Int. J. Pharm, vol.423, pp.26-36, 2012.

A. Escudero, M. E. Calvo, S. Rivera-fernández, J. M. De-la-fuente, and M. Ocaña, Langmuir, vol.29, 1985.

J. Gomez-morales, M. Ia?sco, J. M. Delgado-lópez, S. Sarda, and C. Drouet, Prog. Cryst. Growth Charact. Mater, vol.59, pp.1-46, 2013.

A. Grunenwald, C. Keyser, A. M. Sautereau, E. Crubezy, B. Ludes et al., Appl. Surf. Sci, vol.292, pp.867-875, 2014.

M. Ia?sco, J. M. Delgado-lopez, E. M. Varoni, A. Tampieri, L. Rimondini et al., Small, issue.9, pp.3834-3844, 2013.

I. Rodríguez-ruiz, J. M. Delgado-lópez, M. A. Duran-olivencia, M. Ia?sco, A. Tampieri et al., Langmuir, vol.29, pp.8213-8221, 2013.

M. Ia?sco, C. Drouet, A. Adamiano, P. Pascaud, M. Montesi et al., J. Mater. Chem. B, 2016.

C. Drouet, A. Al-kattan, M. Choimet, A. Tourrette, V. Santran et al., J. Gen. Pract. Med. Diagn, vol.1, pp.1-9, 2015.

C. Sanchez, H. Arribart, and M. M. Girau-guille, Nat. Mater, 2005.

S. V. Dorozhkin, Acta Biomater, vol.6, pp.715-734, 2010.

A. López-macipe, J. Gómez-morales, and R. Rodríguez-clemente, Adv. Mater, vol.10, issue.1, pp.49-53, 1998.

J. Gómez-morales, R. Rodríguez-clemente, B. Armas, C. Combescure, R. Berjoan et al., Langmuir, vol.20, issue.13, pp.5174-5178, 2004.

J. M. Delgado-lópez, M. Ia?sco, I. Rodríguez-ruiz, M. Prat, J. Gómez-morales et al., Acta Biomater, vol.8, pp.3491-3499, 2012.

J. M. Delgado-lópez, R. Frison, A. Cervellino, J. Gómez-morales, A. Guagliardi et al., Adv. Funct. Mater, vol.24, pp.1090-1099, 2014.

M. Ia?sco, G. B. Ramírez-rodríguez, Y. Sakhno, A. Tampieri, G. Martra et al., CrystEngComm, vol.17, pp.507-511, 2015.

Y. Y. Hu, A. Rawal, and K. Schmidt-rohr, Proc. Natl. Acad. Sci. U. S. A, vol.107, pp.22425-224259, 2010.

P. Ivanchenko, J. M. Delgado-lópez, M. Ia?sco, J. Gómez-morales, A. Tampieri et al., , vol.7, p.8901, 2017.

|. Rsc and A. , This journal is © The Royal Society of Chemistry, vol.8, 2018.

, This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence, RSC Advances Paper Open Access Article, 2018.

A. C. Deymier, A. K. Nair, B. Depalle, Z. Qin, K. Arcot et al., Biomaterials, vol.127, pp.75-88, 2017.

F. J. Martínez-casado, M. Ia?sco, J. M. Delgado-lópez, C. Martínez-benito, C. Ruiz-perez et al., Cryst. Growth Des, vol.1, pp.145-153, 2016.

C. Zhang, J. Yang, Z. Quan, P. Yang, C. Li et al., Cryst. Growth Des, vol.9, issue.6, pp.2725-2733, 2009.

N. Döbelin and R. Kleeberg, J. Appl. Crystallogr, vol.48, pp.1573-1580, 2015.

S. Giordano, C. Ponzetto, M. F. Di-renzo, C. S. Cooper, and P. M. Comoglio, Nature, vol.339, issue.6220, pp.155-156, 1989.

E. Villa-moruzzi, S. Lapi, M. Prat, G. Gaudino, and P. M. Comoglio, J. Biol. Chem, issue.24, pp.18176-18180, 1993.

A. Zamperone, S. Pietronave, S. Merlin, D. Colangelo, G. Ranaldo et al., Stem Cells Dev, issue.21, pp.2873-2884, 2013.

N. Vandecandelaere, C. Rey, and C. Drouet, J. Mater. Sci.: Mater. Med, vol.23, pp.2593-2606, 2012.

A. Grunenwald, C. Keyser, A. M. Sautereau, E. Crubezy, B. Ludes et al., J. Archaeol. Sci, vol.49, pp.134-141, 2014.

B. R. Lakshmana, J. Indian Inst. Sci, vol.39, pp.27-29, 1957.

C. Rey, C. Combes, C. Drouet, D. Grossin-;-p.-ducheyne, K. E. Healy et al., Comprehensive Biomaterials, pp.187-221, 2011.

G. Socrates, Infrared and Raman characteristic group frequencies. Tables and charts, 2001.

M. ?upová, Ceram. Int, vol.41, pp.9203-9231, 2015.

A. Al-kattan, P. Dufour, J. Dexpert-ghys, and C. Drouet, J. Phys. Chem. C, vol.114, pp.2918-2924, 2010.

E. A. De-maeyer and R. M. Verbeeck, Bull. Soc. Chim. Belg, vol.102, issue.9, pp.601-609, 1993.

H. Elfeki, J. M. Savariault, and A. B. Salah, J. Alloys Compd, vol.287, pp.114-120, 1999.

I. Hemmilä, S. Dakubu, V. Mukkala, H. Siitaria, and T. Lövgrena, Anal. Biochem, vol.137, pp.335-343, 1984.

F. S. Richardson, Chem. Rev, vol.82, pp.541-552, 1982.

R. Ternane, M. Trabelsi-ayedi, N. Kbir-ariguib, and B. Piriou, J. Lumin, vol.81, pp.165-170, 1999.

A. Al-katan, V. Santran, P. Dufour, J. Dexpert-ghys, and C. Drouet, J. Biomater. Appl, vol.28, pp.697-707, 2014.

J. R. Lakowicz, Principles of Fluorescence Spectroscopy, 2006.

G. G. Guilbault and P. Fluorescence, Tests for In Vitro Cytotoxicity (International Standard Organization, vol.5, pp.50-10993, 1990.

M. I. Khan, A. Mohammad, G. Patil, S. A. Naqvi, L. K. Chauhan et al., Biomaterials, vol.33, pp.1477-1488, 2012.

M. Nedyalkova, B. Donkova, J. Romanova, G. Tzvetkov, S. Madurga et al., Adv. Colloid Interface Sci, vol.249, pp.192-212, 2017.

, Electronic Supplementary Information Luminescent biomimetic citrate-coated europium-doped carbonated apatite particles for use in bioimaging: physico-chemistry and cytocompatibility

J. Gómez-morales-1, *. , and C. Verdugo, Jorge Fernando Fernández-Sánchez, vol.1

, IACT (CSIC-UGR), Avda. Las Palmeras

. Armilla,

, UMR CNRS/INPT/UPS 5085, Ensiacet, 4 allée Emile Monso, 31030 Toulouse cedex 4

, Via Solaroli, vol.17, p.28100

, Avda. Fuentenueva s/n, 18071 Granada, Spain. * Corresponding author: jaime@lec.csic.es

, Electronic Supplementary Material (ESI) for RSC Advances, This journal is © The Royal Society of Chemistry, 2017.