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Aqueous Ring-Opening Polymerization-Induced Self-Assembly (ROPISA) of N-carboxyanhydrides

Abstract : We report the first aqueous ring‐opening polymerization (ROP) of N‐carboxyanhydrides (NCA) using α‐amino‐poly(ethylene oxide) macroinitiator to protect NCA monomers from hydrolysis through spontaneous in situ self‐assembly (ISA). This ROPISA process affords well‐defined amphiphilic diblock copolymers that simultaneously form original needle‐like nano‐objects.
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https://hal.archives-ouvertes.fr/hal-02333682
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Submitted on : Wednesday, November 6, 2019 - 4:46:35 PM
Last modification on : Wednesday, June 9, 2021 - 12:22:02 PM
Long-term archiving on: : Saturday, February 8, 2020 - 3:09:05 AM

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Chloé Grazon, Pedro Salas-Ambrosio, Emmanuel Ibarboure, Alix Buol, Elisabeth Garanger, et al.. Aqueous Ring-Opening Polymerization-Induced Self-Assembly (ROPISA) of N-carboxyanhydrides. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2020, 59 (2), pp.622-626. ⟨10.1002/anie.201912028⟩. ⟨hal-02333682⟩

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