First detection of a key intermediate in the oxidation of fuel + NO systems: HONO

Lorena Marrodán (1) , Yu Song (2) , Olivier Herbinet (2) , María U Alzueta (1) , Christa Fittschen (3) , Yiguang Ju (4) , Frédérique Battin-Leclerc (2)

1 I3A - Aragón Institute of Engineering Research [Zaragoza]
2 LRGP - Laboratoire Réactions et Génie des Procédés
3 PC2A - Physicochimie des Processus de Combustion et de l’Atmosphère - UMR 8522
4 MAE - Department of Mechanical and Aerospace Engineering [Princeton]

This paper reports the first online gas phase detection of absolute concentrations of HONO under engine relevant conditions, during the oxidation of an alkane in the presence of NO x. The detection was achieved at laboratory scale thanks to the coupling of a jet-stirred reactor to a continuous-wave Cavity Ring-Down Spectroscopy cell. The evidence of the formation of HONO was obtained by comparing measured cw-CRDS spectra with a literature one. The formation of HONO was simultaneously observed with the appearance of another nitrogen compound: NO 2. This confirms that HONO could also be formed from NO 2 under engine conditions.

Domaines: Chimie

Lorena Marrodán, Yu Song, Olivier Herbinet, María U Alzueta, Christa Fittschen, et al.. First detection of a key intermediate in the oxidation of fuel + NO systems: HONO. Chemical Physics Letters, 2019, 719, pp.22-26. ⟨10.1016/j.cplett.2019.01.038⟩. ⟨hal-02321963⟩