Complete determination of natural site-specific enantio-isotopomeric excesses in linoleic acid using natural abundance deuterium 2D NMR in polypeptide mesophases - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2010

Complete determination of natural site-specific enantio-isotopomeric excesses in linoleic acid using natural abundance deuterium 2D NMR in polypeptide mesophases

Résumé

NAD 2D NMR spectroscopy using chiral mesophases made of poly-gamma-benzyl-L-glutamate and pyridine allowed us to evaluate, for the first time, the natural site-specific enantio-isotopomeric excesses at each methylene group of linoleic acid, a central, essential PUFA precursor of all conjugated triene fatty acids.

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hal-02143503 , version 1 (29-05-2019)

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Zeinab Serhan, Laura Martel, Isabelle Billault, Philippe Lesot. Complete determination of natural site-specific enantio-isotopomeric excesses in linoleic acid using natural abundance deuterium 2D NMR in polypeptide mesophases. Chemical Communications, 2010, 46 (35), pp.6599-6601. ⟨10.1039/c0cc01486a⟩. ⟨hal-02143503⟩
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