Empirical determination of the absolute configuration of small chiral molecules using natural abundance 2H NMR in chiral liquid crystals

Latifa Ziani (1) , Philippe Lesot (1, 2) , Abdelkhrim Meddour (1) , Jacques Courtieu (1)

1 ICMMO - Institut de Chimie Moléculaire et des Matériaux d'Orsay
2 CNRS - Centre National de la Recherche Scientifique

Natural abundance deuterium 2D NMR spectroscopy in polypeptide liquid crystals is used for empirically determining the absolute configuration of small chiral molecules.

Mots clés: Chiral liquid cystals; Natural abundance; NMR; Deuterium; PBLG; Absolute configuration

Domaines: Chimie analytique; Chimie théorique et/ou physique

Latifa Ziani, Philippe Lesot, Abdelkhrim Meddour, Jacques Courtieu. Empirical determination of the absolute configuration of small chiral molecules using natural abundance 2H NMR in chiral liquid crystals. Chemical Communications, 2007, 45, pp.4737. ⟨10.1039/b711493a⟩. ⟨hal-02310959⟩