(Cover Profile) 2H and 13C NMR-Based Enantiodetection Using Polyacetylene versus Polypeptide Aligning Media: Versatile and Complementary Tools for Chemists

Abstract : Invited for this month’s cover are the collaborating groups of Dr. Philippe Lesot (DR CNRS) at Universit Paris-Sud/Universit Paris-Saclay, France, and Professor Michael Reggelin at TU Darmstadt, Germany. The cover shows the proton-decoupled natural abundance deuterium (NAD-{1H}) Q-resolved Fz 2D-NMR spectrum of ()-3-methylhexane measured in the anisotropic lyotropic chiral liquid-crystalline phase formed by a concentrated solution of a helically chiral polyarylacetylene in chloroform solvent. Seventeen out of the twenty possible deuterium quadrupolar doublets are observed, demonstrating the enormous enantiodifferentiating capability of the system, even for an unfunctionalized chiral alkane. Read the full text of the article at 10.1002/cplu.201800493.
Keywords : Cover profile
Document type :
Journal articles
Complete list of metadatas

https://hal.archives-ouvertes.fr/hal-02308742
Contributor : Philippe Lesot <>
Submitted on : Tuesday, October 8, 2019 - 4:51:08 PM
Last modification on : Monday, November 11, 2019 - 11:25:57 PM

Licence


Copyright

Identifiers

Collections

Citation

Philippe Lesot, Philippe Berdagué, Abdelkrim Meddour, Alexander Kreiter, Markus Noll, et al.. (Cover Profile) 2H and 13C NMR-Based Enantiodetection Using Polyacetylene versus Polypeptide Aligning Media: Versatile and Complementary Tools for Chemists. ChemPlusChem, Wiley, 2019, pp.143-143. ⟨10.1002/cplu.201800584⟩. ⟨hal-02308742⟩

Share

Metrics

Record views

26