Synthesis, structure and magnetic properties of a series of Ln( iii ) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2019

Synthesis, structure and magnetic properties of a series of Ln( iii ) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization

Résumé

We report the investigation of synthesis, structure and magnetic properties of a series of homoleptic Ln(III) complexes coordinated by radical-anionic iminopyridine ligands of general formula [Ln(IPy)3]·solv (IPy = iminopyridine; Ln = Tb, Dy, Er, Y, Gd). The dysprosium analogue exhibits a zero-field Single-Molecule Magnet (SMM) behavior.
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hal-02270823 , version 1 (26-11-2020)

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Jérôme Long, Grigorii Skvortsov, Anton Cherkasov, Konstantin A. Lyssenko, Andrei Poddel'Sky, et al.. Synthesis, structure and magnetic properties of a series of Ln( iii ) complexes with radical-anionic iminopyridine ligands: effect of lanthanide ions on the slow relaxation of the magnetization. Dalton Transactions, 2019, 48 (32), pp.12018-12022. ⟨10.1039/C9DT00738E⟩. ⟨hal-02270823⟩
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