Chemical kinetics in an atmospheric pressure helium plasma containing humidity

Sandra Schröter (1) , Apiwat Wijaikhum (1) , Andrew Gibson (2, 1) , Andrew West (1) , Helen Davies (1) , Nicolas Minesi (3) , James Dedrick (1) , Erik Wagenaars (1) , Nelson de Oliveira (4) , Laurent Nahon (5) , Mark Kushner (6) , Jean-Paul Booth (7) , Kari Niemi (1) , Timo Gans (1) , Deborah O'Connell (1)

1 YPI - York Plasma Institute
2 University of Liverpool
3 EM2C - Laboratoire d'Énergétique Moléculaire et Macroscopique, Combustion
4 SSOLEIL - Synchrotron SOLEIL
5 Ligne DESIRS [Saint Aubin]
6 Computer Science department [Michigan Tech]
7 LPP - Laboratoire de Physique des Plasmas

a Atmospheric pressure plasmas are sources of biologically active oxygen and nitrogen species, which makes them potentially suitable for the use as biomedical devices. Here, experiments and simulations are combined to investigate the formation of the key reactive oxygen species, atomic oxygen (O) and hydroxyl radicals (OH), in a radio-frequency driven atmospheric pressure plasma jet operated in humidified helium. Vacuum ultraviolet high-resolution Fourier-transform absorption spectroscopy and ultraviolet broad-band absorption spectroscopy are used to measure absolute densities of O and OH. These densities increase with increasing H 2 O content in the feed gas, and approach saturation values at higher admixtures on the order of 3 Â 10 14 cm À3 for OH and 3 Â 10 13 cm À3 for O. Experimental results are used to benchmark densities obtained from zero-dimensional plasma chemical kinetics simulations, which reveal the dominant formation pathways. At low humidity content, O is formed from OH + by proton transfer to H 2 O, which also initiates the formation of large cluster ions. At higher humidity content, O is created by reactions between OH radicals, and lost by recombination with OH. OH is produced mainly from H 2 O + by proton transfer to H 2 O and by electron impact dissociation of H 2 O. It is lost by reactions with other OH molecules to form either H 2 O + O or H 2 O 2. Formation pathways change as a function of humidity content and position in the plasma channel. The understanding of the chemical kinetics of O and OH gained in this work will help in the development of plasma tailoring strategies to optimise their densities in applications.

Domaines: Physique des plasmas [physics.plasm-ph]

Sandra Schröter, Apiwat Wijaikhum, Andrew Gibson, Andrew West, Helen Davies, et al.. Chemical kinetics in an atmospheric pressure helium plasma containing humidity. Physical Chemistry Chemical Physics, 2018, 20 (37), pp.24263-24286. ⟨10.1039/c8cp02473a⟩. ⟨hal-02266591⟩