, Mixed-Component Metal-Organic Frameworks

, Enhancing Functionality through Solid Solution Formation and Surface Modifications, Chem. Eur. J, vol.13, pp.818-827, 2011.

H. Deng, C. J. Doonan, H. Furukawa, and R. , Multiple Functional Groups of Varying Ratios in MetalOrganic Frameworks

B. Ferreira, J. Towne, C. B. Knobler, B. Wang, and O. M. Yaghi, Science, vol.327, pp.846-850, 2010.

T. Park, K. Koh, A. G. Wongfoy, A. J. Matzger, ;. Liu et al., Systematic Ligand Modulation Enhances the Moisture Stability and Gas Sorption Characteristics of Quaternary Metal-Organic Frameworks, 'Nonlinear Properties in Coordination Copolymers Derived from Randomly Mixed Ligands, vol.11, pp.3901-3909, 2011.

A. Dutta, A. G. Wong-foy, and A. J. Matzger, Exceptional Surface Area from Coordination Copolymers Derived from Two Linear Linkers of Differing Lengths, Chem. Sci, vol.5, pp.3729-3734, 2014.

. Matzger, Chem. Sci, vol.2012, pp.2429-2432

, Coordination Copolymerization Mediated by Zn 4 o(Co 2 r) 6

&. K. Geometry, A. G. Koh, A. J. Wong-foy, ;. Matzger, V. Grunker et al., A New Metal-Organic Framework with Ultra-High Surface Area, Metal Clusters: A Balancing Act between Statistics, vol.132, pp.15005-15010, 2010.

I. Mueller, S. Senkovska, and . Kaskel, Copolymerisation at Work: The First Example of a Highly Porous Mof Comprising a Triarylborane-Based Linker, Chem. Commun, vol.50, pp.3450-3452, 2014.

B. Helten, V. Sahoo, I. Bon, S. Senkovska, F. Kaskel et al., Route to a Family of Robust, Non-Interpenetrated MetalOrganic Frameworks with Pto-Like Topology, CrystEngComm, vol.17, pp.307-312, 2015.

B. Schlichtenmayer, U. Streppel, S. Mueller, M. Leoni, S. Hirscher et al., Postsynthetic Paddle-Wheel Cross-Linking and Functionalization of 1,3-Phenylenebis(Azanetriyl)TetrabenzoateBased Mofs, Chem. Eur. J, vol.17, pp.2460-2467, 2011.

, Ultrahigh Porosity in Metal-Organic Frameworks

N. Furukawa, Y. B. Ko, N. Go, S. B. Aratani, E. Choi et al.,

Ö. Yazaydin, R. Q. Snurr, M. O'keeffe, J. Kim, and O. M. Yaghi, Science, vol.329, pp.424-428, 2010.

, A Non-Regular Layer Arrangement of a Pillared-Layer Coordination Polymer: Avoiding Interpenetration Via Symmetry Breaking at Nodes

. Matzger, Chem. Commun, vol.51, pp.13611-13614, 2015.

K. Koh, A. G. Wong-foy, and A. J. Matzger, A Crystalline Mesoporous Coordination Copolymer with High Microporosity, Angew. Chem., Int. Ed, vol.47, pp.677-680, 2008.

, Defect-Engineered Metal-Organic Frameworks

D. E. Bueken, R. A. De-vos, and . Fischer, Angew. Chem., Int. Ed, vol.54, pp.7234-7254, 2015.

, Ordered Vacancies and Their Chemistry in Metal-Organic Frameworks

. Li, J. Am. Chem. Soc, vol.136, pp.14465-14471, 2014.

, Synthesis Modulation as a Tool to Increase the Catalytic Activity of Metal-Organic Frameworks: The Unique Case of Uio-66(Zr)

M. Voorde, K. Vandichel, A. Houthoofd, M. Vimont, and M. Daturi,

V. Waroquier, C. Van-speybroeck, D. E. Kirschhock, and . De-vos, Correlated Defect Nanoregions in a Metal-Organic Framework, J. Am. Chem. Soc, vol.135, 2013.

M. G. Kleppe, H. Tucker, N. P. Wilhelm, F. X. Funnell, A. L. Coudert et al., Assessing Chemical Heterogeneity at the Nanoscale in Mixed-Ligand Metal-Organic Frameworks with the Ptir Technique, Angew. Chem. Int. Ed, vol.5, pp.2852-2856, 2014.

, A Non-Interpenetrated Porous Metal-Organic Framework with High Gas-Uptake Capacity, Chem. Commun, vol.47, pp.9861-9863, 2011.

, Route to a Family of Robust, Non-Interpenetrated MetalOrganic Frameworks with Pto-Like Topology

I. A. Senkovska, R. Baburin, U. Grünker, and M. Stoeck,

B. Schlichtenmayer, U. Streppel, S. Mueller, M. Leoni, S. Hirscher et al., Chem. Eur. J, vol.17, pp.13007-13016, 2011.

, Connection of Zinc Paddle-Wheels in a Pto-Type MetalOrganic Framework with 2-Methylimidazolate and Subsequent Incorporation of Charged Organic Guests

H. J. Sung, S. Y. Park, J. Park, and . Kim, Chem. Commun, vol.50, pp.6785-6788, 2014.

, The Reticular Chemistry Structure Resource (Rcsr) Database of, and Symbols for, Crystal Nets

J. Ramsden and O. M. Yaghi, Topological Analysis of Metal-Organic Frameworks with Polytopic Linkers and/or Multiple Building Units and the, Acc. Chem. Res, vol.41, pp.1782-1789, 2008.

&. M. Minimal-transitivity-principle, D. Li, M. Li, and O. O'keeffe,

M. Yaghi, Metastable Interwoven Mesoporous Metal-Organic Frameworks, Chem. Rev, vol.114, pp.1343-1370, 2013.

S. Fronczek, S. T. Parkin, M. Hyde, B. O'keeffe, and . Chen, Isoreticular Expansion of Metal-Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals, Inorg. Chem, vol.52, pp.11580-11584, 2013.

K. Park, F. J. Uribe-romo, J. Kim, M. O'keeffe, and O. ,

I. Yaghi and . Chem, Polymorphism of Metal-Organic Frameworks: Direct Comparison of Structures and Theoretical N 2 -Uptake of, vol.50, pp.9147-9152, 2011.

T. Pto, -. Tbo-isomers, &. N. Zhu, M. J. Lennox, T. Duren et al., Assembly of Two 3d Porous Metal-Organic Frameworks Based on 1,2,3-Triazole-4,5-Dicarboxylate Exhibiting Novel Coordination Modes, Cryst. Growth Des, vol.50, pp.5456-5461, 2012.

K. Senkovska, U. Gedrich, A. Stoeck, U. Henschel, S. Mueller et al., Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4o(Tca)2] Having the Pyrite Topology, Angew. Chem., Int. Ed, vol.48, pp.3907-3909, 2003.

, Preparation and Characterization of Divalent Cobalt, Nickel, Zinc, Cadmium and Monovalent Silver Nitrate Complexes with 4.4?-Bipyridine, J. Inorg. Nucl. Chem, vol.40, pp.924-926, 1978.

S. R. Petrusenko, J. Sieler, and V. , Direct Synthesis of Zinc and Nickel(Ii) Complexes with, vol.1, p.4

Z. Kokozay and . Naturforsch, Secondary Building Units, Nets and Bonding in the Chemistry of Metal-Organic Frameworks, Chem. Sci, vol.52, pp.331-336, 1997.

M. Mendoza-cortes, O. M. O'keeffe, and . Yaghi, Chem. Soc. Rev, vol.38, pp.1257-1283, 2009.

;. S. 'enantiopure-vs, J. R. Garibay, Z. Stork, S. M. Wang, S. G. Cohen et al., Racemic Metalloligands: Impact on MetalOrganic Framework Structure and Synthesis, Chem. Commun, pp.4881-4883, 2007.

M. Zhao, J. Su, J. Zhang, J. Wu, and Y. Tian, While this work was in progress the structure of MUF-21 was reported elsewhere, vol.71, pp.799-803, 2015.

, Control over Flexibility of Entangled Porous Coordination Frameworks by Molecular and Mesoscopic Chemistries

Y. Furukawa, S. Sakata, and . Kitagawa, Chem. Lett, vol.42, pp.570-576, 2013.

, Soft Porous Crystals

. Kitagawa, Nat Chem, vol.1, pp.695-704, 2009.

, Stability and Hydrolyzation of Metal Organic Frameworks with Paddle-Wheel Sbus Upon Hydration

Q. Canepa, J. Gong, T. Li, and Y. J. Thonhauser, Reversible Two-Dimensional?Three Dimensional Framework Transformation within a Prototype Metal?Organic Framework, Cryst. Growth Des, vol.24, pp.5293-5296, 2009.

, A Simple and Rational Approach for Binodal Metal-Organic Frameworks with Tetrahedral Nodes and Unexpected Multimodal Porosities from Nonstoichiometric Defects, Cryst. Growth Des, vol.14, 1998.

D. L. Sumida, J. A. Rogow, T. M. Mason, and E. Mcdonald,

Z. R. Bloch, T. Herm, J. R. Bae, and . Long, Chem. Rev, vol.112, pp.724-781, 2012.

&. A. Ortiz, A. Boutin, A. H. Fuchs, and F. Coudert, Metal-Organic Frameworks with Wine-Rack Motif: What Determines Their Flexibility and Elastic Properties?, Phys. Rev. Lett, vol.109, pp.174703-174708, 2012.
URL : https://hal.archives-ouvertes.fr/hal-02116910

, Zeolitic Imidazole Frameworks: Structural and Energetics Trends Compared with Their Zeolite Analogues

B. Coudert, A. K. Slater, C. Cheetham, and . Mellot-draznieks, CrystEngComm, vol.11, pp.2272-2276, 2009.

, Defect-Dependent Colossal Negative Thermal Expansion in Uio-66(Hf) Metal-Organic Framework, APL Materials, vol.2, pp.124110-124119, 2014.

A. Murray, F. Coudert, and A. L. Goodwin, Exploiting Chemically Selective Weakness in Solids as a Route to New Porous Materials, Phys. Chem. Chem. Phys, vol.17, pp.381-388, 2015.

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