Rotational Dynamics of Linkers in Metal–Organic Frameworks - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Nanomaterials Année : 2019

Rotational Dynamics of Linkers in Metal–Organic Frameworks

Résumé

Among the numerous fascinating properties of metal–organic frameworks (MOFs), their rotational dynamics is perhaps one of the most intriguing, with clear consequences for adsorption and separation of molecules, as well as for optical and mechanical properties. A closer look at the rotational mobility in MOF linkers reveals that it is not only a considerably widespread phenomenon, but also a fairly diverse one. Still, the impact of these dynamics is often understated. In this review, we address the various mechanisms of linker rotation reported in the growing collection of literature, followed by a highlight of the methods currently used in their study, and we conclude with the impacts that such dynamics have on existing and future applications.
Fichier principal
Vignette du fichier
nanomaterials-09-00330-v3.pdf (10.33 Mo) Télécharger le fichier
Origine : Fichiers éditeurs autorisés sur une archive ouverte
Loading...

Dates et versions

hal-02264108 , version 1 (06-08-2019)

Identifiants

Citer

Adrian Gonzalez-Nelson, François-Xavier Coudert, Monique A van Der Veen. Rotational Dynamics of Linkers in Metal–Organic Frameworks. Nanomaterials, 2019, 9 (3), pp.330. ⟨10.3390/nano9030330⟩. ⟨hal-02264108⟩
43 Consultations
19 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More