Multiple photosynthetic reaction centres of porphyrinic polypeptide–Li + @C 60 supramolecular complexes

Kei Ohkubo (1, 2) , Tetsuya Hasegawa (1) , Régis Rein (3) , Nathalie Solladié (3) , Shunichi Fukuzumi (1, 2, 4, 5)

1 Department of Material and Life Science, Graduate School of Engineering, Osaka University
2 Department of Chemistry and Nano Science
3 LCC - Laboratoire de chimie de coordination
4 Meijo University
5 JST - Japan Science and Technology Agency

Multiple photosynthetic reaction centres have been successfully constructed using strong supramolecular complexes of free base porphyrin polypeptides with lithium ion-encapsulated C60 (Li+@C60) as compared with those of C60. Efficient energy migration and electron transfer occur in the supramolecular complexes.

Domaines: Chimie de coordination

Kei Ohkubo, Tetsuya Hasegawa, Régis Rein, Nathalie Solladié, Shunichi Fukuzumi. Multiple photosynthetic reaction centres of porphyrinic polypeptide–Li + @C 60 supramolecular complexes. Chemical Communications, 2015, 51 (99), pp.17517-17520. ⟨10.1039/C5CC07203D⟩. ⟨hal-02117143⟩