Crystal structure of (±)-1-({[4-(allyloxy)phenyl]sulfanyl}methyl)-2-(diphenylthiophosphoryl)ferrocene

Audric Michelot (1) , Stéphanie Sarda (2) , Jean-Claude Daran (1) , Éric Deydier (1) , Eric Manoury (1)

1 LCC - Laboratoire de chimie de coordination
2 CIRIMAT - Centre interuniversitaire de recherche et d'ingenierie des matériaux

The title compound, [Fe(C5H5)(C27H24OPS2)], is built up from a ferrocene moiety substituted in the 1- and 2-positions by {[4-(all­yloxy)phen­yl]sulfan­yl}methyl and di­phenyl­thio­phosphoryl groups, respectively. The two S atoms lie on opposite sides of the cyclo­penta­dienyl ring plane to which they are attached. In the crystal, C-H...S hydrogen bonds link the mol­ecules into a ribbon running parallel to the (-110) plane. C-H...[pi] inter­actions link the ribbons to form a three-dimensional network.

Domaines: Chimie de coordination; Cristallographie

Audric Michelot, Stéphanie Sarda, Jean-Claude Daran, Éric Deydier, Eric Manoury. Crystal structure of (±)-1-({[4-(allyloxy)phenyl]sulfanyl}methyl)-2-(diphenylthiophosphoryl)ferrocene. Acta crystallographica Section E : Crystallographic communications [2015-..], 2015, 71 (8), pp.972-975. ⟨10.1107/S2056989015013560⟩. ⟨hal-02114261⟩