An SFG/DFG investigation of CN− adsorption at an Au electrode in 1-butyl-1-methyl-pyrrolidinium bis(trifluoromethylsulfonyl) amide ionic liquid
Résumé
In this paper we report an SFG/DFG investigation of the adsorption of CN À-used as a probe molecule to study the electrochemical double-layer structure-at a polycrystalline Au electrode in 1-butyl-1-methyl-pyrrolidinium bis(trifluoromethylsulfonyl) amide ([BMP][TFSA]) room-temperature ionic liquid (RTIL). The adsorption of CN À yielded single SFG and DFG bands in the range from ca. 2125 to 2135 cm À1 , exhibiting a Stark tuning of ca. 3 cm À1 V À1. Vibrational resonances-corresponding to modes of the RTIL coad-sorbed with CN À , were found in the range from ca. 1200 to 1500 cm À1. The study of the double-layer structure was complemented by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) measurements, from which the differential double-layer capacity (C DL) was estimated.