Lanthanide complexes with pivaloylacetone

Svetlana V. Eliseeva (1) , N.V Chugarov , N.P Kuz'Mina , Rita Nichiporuk , Sergei A Ivanov , L.I Martynenko

1 MSU - Lomonosov Moscow State University

Complexes Ln(pa)3·2H2O (Ln=La, Gd, Lu, Hpa - pivaloylacetone) are synthesized and investigated by the methods of element, IR spectroscopic and thermal analyses. Behaviour of the complexes during heating in vacuum is compared with such one for acetylacetonates and dipivaloylmethanates. Structure of the complexes in solution is studied by 1H NMR and MALDI-MS

Domaines: Chimie; Chimie inorganique

Svetlana V. Eliseeva, N.V Chugarov, N.P Kuz'Mina, Rita Nichiporuk, Sergei A Ivanov, et al.. Lanthanide complexes with pivaloylacetone. Russian Journal of Inorganic Chemistry / Zhurnal Neorganicheskoi Khimii, 2003, 48, pp.1014-1019. ⟨hal-02103379⟩