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Article Dans Une Revue Inorganica Chimica Acta Reviews Année : 2012

Binuclear copper(II) complexes 1: Synthesis, characterization and evaluation of a new complex in phosphatase-like activity

Résumé

A new binuclear Cu(II) complex derived from a pamoic type ligand has been synthesized and characterized by X-ray crystallography. This complex was checked as catalysts in the hydrolysis of bis(p-nitro-phenyl)phosphate. Its catalytic properties were studied at various pH and compared to the mononuclear Cu(II) complex. At pH 5.38, the binuclear Cu(II) complex exhibited a phosphatase-like activity with 11 TON and 24% conversion and was found to be 41-fold more active than the mononuclear counterpart.

Domaines

Chimie

Dates et versions

hal-02091433 , version 1 (09-04-2019)

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Citer

Olivier Schicke, Bruno Faure, Michel Giorgi, A. Jalila Simaan, Marius Réglier. Binuclear copper(II) complexes 1: Synthesis, characterization and evaluation of a new complex in phosphatase-like activity. Inorganica Chimica Acta Reviews, 2012, 391, pp.189-194. ⟨10.1016/j.ica.2012.04.019⟩. ⟨hal-02091433⟩
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