Mono- and Terfluorene Oligomers as Versatile Sensitizers for the Luminescent Eu 3+ Cation

Abstract : We present the design, synthesis, and physical and photophysical characterization of Eu(3+) and Gd(3+) complexes formed with two ligands bearing either one or three fluorene sensitizer units. As a novel sensitizing approach, the oligomer length is used to control the energies of the triplet states of the sensitizer and to mediate the sensitizer to lanthanide energy transfer.
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https://hal.archives-ouvertes.fr/hal-02090881
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Submitted on : Friday, April 5, 2019 - 11:27:40 AM
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D Samuel Oxley, Robert Walters, James Copenhafer, Tara Meyer, Stephane Petoud, et al.. Mono- and Terfluorene Oligomers as Versatile Sensitizers for the Luminescent Eu 3+ Cation. Inorganic Chemistry, American Chemical Society, 2009, 48 (14), pp.6332-6334. ⟨10.1021/ic9002324⟩. ⟨hal-02090881⟩

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