A Strategy to Protect and Sensitize Near-Infrared Luminescent Nd 3+ and Yb 3+ : Organic Tropolonate Ligands for the Sensitization of Ln 3+ -Doped NaYF 4 Nanocrystals

Jian Zhang , Chad Shade , Demetra Chengelis , Stephane Petoud (1)

1 Department of Chemistry (University of Pittsburgh)

A strategy to sensitize and protect near-infrared (NIR) emitting Nd3+ and Yb3+ is presented. Combining protection provided by the inorganic matrix of NaYF4 nanocrystals and sensitization from tropolonate ligands capped on their surface, the lanthanide cation centered luminescence was observed through the ligand excitation. The extended lanthanide luminescence lifetimes indicate the success of this strategy.

Domaines: Chimie

Jian Zhang, Chad Shade, Demetra Chengelis, Stephane Petoud. A Strategy to Protect and Sensitize Near-Infrared Luminescent Nd 3+ and Yb 3+ : Organic Tropolonate Ligands for the Sensitization of Ln 3+ -Doped NaYF 4 Nanocrystals. Journal of the American Chemical Society, 2007, 129 (48), pp.14834-14835. ⟨10.1021/ja074564f⟩. ⟨hal-02090833⟩