Brilliant Sm, Eu, Tb, and Dy Chiral Lanthanide Complexes with Strong Circularly Polarized Luminescence

Stephane Petoud (1) , Gilles Muller , Evan Moore , Jide Xu , Jurek Sokolnicki , James Riehl , Uyen Le , Seth Cohen , Kenneth Raymond

1 institute of analytical and inorganic Chemistry

The synthesis, characterization, and luminescent behavior of trivalent Sm, Eu, Dy, and Tb complexes of two enantiomeric, octadentate, chiral, 2-hydroxyisophthalamide ligands are reported. These complexes are highly luminescent in solution. Functionalization of the achiral parent ligand with a chiral 1-phenylethylamine substituent on the open face of the complex in close proximity to the metal center yields complexes with strong circularly polarized luminescence (CPL) activity. This appears to be the first example of a system utilizing the same ligand architecture to sensitize four different lanthanide cations and display CPL activity. The luminescence dissymmetry factor, g(lum), recorded for the Eu(III) complex is one of the highest values reported, and this is the first time the CPL effect has been demonstrated for a Sm(III) complex with a chiral ligand. The combination of high luminescence intensity with CPL activity should enable new bioanalytical applications of macromolecules in chiral environments.

Domaines: Chimie

Stephane Petoud, Gilles Muller, Evan Moore, Jide Xu, Jurek Sokolnicki, et al.. Brilliant Sm, Eu, Tb, and Dy Chiral Lanthanide Complexes with Strong Circularly Polarized Luminescence. Journal of the American Chemical Society, 2007, 129 (1), pp.77-83. ⟨10.1021/ja064902x⟩. ⟨hal-02090687⟩