New route to carbonate-functionalized imidazolium and pyrrolidinium-based ionic liquids

H. Srour (1) , W. Darwich (1) , F. Lindl (1) , P. Husson (2) , H. Rouault (3) , C. Santini (1)

1 C2P2 - Laboratoire de Chimie, Catalyse, Polymères et Procédés, R 5265
2 ICCF - Institut de Chimie de Clermont-Ferrand
3 LITEN - Laboratoire d'Innovation pour les Technologies des Energies Nouvelles et les nanomatériaux

A new, versatile, and green route to access ionic liqs. contg. carbonate groups, including 1-[2-(propyloxycarbonyloxy)ethyl]-3-Me imidazolium and N-methyl-N-[2-(propyl-oxcarbonyl) ethyl] pyrrolidinium assocd. with a bis(trifluoromethane)sulfonimide anion, [C1(C2O(CO)OC3)Im][NTf2] and [C1(C2O(CO)OC3)Py][NTf2], has been developed and characterized. The key point of this route is to avoid the metathesis reaction step with LiNTf2, which could result in ionic liqs. that are highly contaminated with LiCl salt through the coordination of lithium ions by the carbonate group. [on SciFinder(R)]

Mots clés: imidazolium pyrrolidinium carbonate functionalized ionic liq prepn green

Domaines: Chimie

H. Srour, W. Darwich, F. Lindl, P. Husson, H. Rouault, et al.. New route to carbonate-functionalized imidazolium and pyrrolidinium-based ionic liquids. New J. Chem., 2017, 41 (20), pp.11915-11920. ⟨hal-02087083⟩