On the extension of the atherton-todd reaction to the pentacoordinated phosphorus compounds. synthesis of new bicyclophosphoranes containing macrocycles

Abstract : The three macrocycles 5, 6, 7 with 10, 16 and 22 links, bearing two bicyclophosphoranes moieties are synthesized by the Atherton-Todd reaction carried out with the bis(hydridobicyclophosphoranes) 2, 3, 4. This result confirms the generality of this reaction leading to new families of bis(bicyclophosphoranes) containing macrocycles.
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Marie-Rose Mazières, Douraid Houalla, Marie-Carmen Monje, Michel Sanchez. On the extension of the atherton-todd reaction to the pentacoordinated phosphorus compounds. synthesis of new bicyclophosphoranes containing macrocycles. Phosphorus, Sulfur, and Silicon and the Related Elements, Taylor & Francis, 1993, 83 (1-4), pp.157-161. ⟨10.1080/10426509308034358⟩. ⟨hal-02066361⟩

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