Magnesium and calcium silicate hydrates, Part I: Investigation of the possible magnesium incorporation in calcium silicate hydrate (C-S-H) and of the calcium in magnesium silicate hydrate (M-S-H)

Ellina Bernard , Barbara Lothenbach (1) , Céline Cau-Dit-Coumes (2) , Christophe Chlique , Alexandre Dauzeres (3, 4) , Isabelle Pochard (5, 6)

1 Laboratory for Concrete & Construction Chemistry
2 Commissariat à l'energie Atomique et aux Energies Alternatives
3 IRSN/PRP-DGE/SRTG/LETIS - Laboratoire d'Etude et de recherche sur les Transferts et les Installations dans les Sols
4 IRSN/PSE-ENV/SEDRE/LETIS - Laboratoire d'étude et de recherche sur les transferts et les interactions dans les sous-sols
5 ICB - Laboratoire Interdisciplinaire Carnot de Bourgogne
6 UTINAM - Univers, Transport, Interfaces, Nanostructures, Atmosphère et environnement, Molécules (UMR 6213)

Calcium silicate hydrate (C-S-H) and magnesium silicate hydrate (M-S-H) have been described as two separate phases. This work investigates their stability domains and the possible uptake of small amounts of magnesium by C-S-H or, reversely, the uptake of small amounts of calcium by M-S-H. The phases, synthesized by co-precipitation, are characterized using a large panel of techniques (thermogravimetry analysis, X-ray diffraction, Xray pair distribution function analysis, 29Si MAS-NMR spectroscopy, measurement of zeta potential and cation exchange capacity) while the compositions of the solutions at equilibrium are determined by ion chromatography and pH measurements. Syntheses of C-S-H samples in the presence of magnesium ((Ca + Mg)/Si = 0.80 and Mg/Si = 0.05 or 0.10) yield two separate phases: C-S-H and M-S-H. There is no experimental evidence of any uptake of magnesium by C-S-H. On the contrary, when M-S-H samples are synthesized in the presence of calcium ((Ca + Mg)/Si = 0.80 and Ca/Si = 0.05 or 0.10), the low pH of the suspension (9–10) prevents the formation of C-S-H but favors the precipitation of M-S-H with small amounts of calcium. This latter may be sorbed onto the surface of M-S-H to outbalance its negative charges and/or incorporated into the interlayer, as suggested by small structural changes.

Domaines: Chimie

Ellina Bernard, Barbara Lothenbach, Céline Cau-Dit-Coumes, Christophe Chlique, Alexandre Dauzeres, et al.. Magnesium and calcium silicate hydrates, Part I: Investigation of the possible magnesium incorporation in calcium silicate hydrate (C-S-H) and of the calcium in magnesium silicate hydrate (M-S-H). Applied Geochemistry, 2018, 89, pp.229-242. ⟨10.1016/j.apgeochem.2017.12.005⟩. ⟨hal-02021043⟩