Quantification of the Keto-Hydroperoxide (HOOCH 2 OCHO) and Other Elusive Intermediates during Low-Temperature Oxidation of Dimethyl Ether

Kai Moshammer (1) , Ahren Jasper , Denisia Popolan-Vaida , Zhandong R Wang (2) , Vijai Shankar Bhavani Shankar , Lena Ruwe , Craig Taatjes , Philippe Dagaut (3) , Nils Hansen

1 PTB - Physikalisch-Technische Bundesanstalt [Braunschweig]
2 NSRL - National Synchrotron Radiation Laboratory
3 ICARE - Institut de Combustion, Aérothermique, Réactivité et Environnement

Mots clés: Jet-stirred reactor; Oxidation -mechanism; peroxides; dimethylether; ketohydroperoxides

Domaines: Chimie théorique et/ou physique; Milieux fluides et réactifs

Kai Moshammer, Ahren Jasper, Denisia Popolan-Vaida, Zhandong R Wang, Vijai Shankar Bhavani Shankar, et al.. Quantification of the Keto-Hydroperoxide (HOOCH 2 OCHO) and Other Elusive Intermediates during Low-Temperature Oxidation of Dimethyl Ether. Journal of Physical Chemistry A, 2016, 120 (40), pp.7890-7901. ⟨10.1021/acs.jpca.6b06634⟩. ⟨hal-02014671⟩