The In situ growth of Nanostructures on Surfaces (INS) endstation of the ESRF BM32 beamline: a combined UHV–CVD and MBE reactor for in situ X-ray scattering investigations of growing nanoparticles and semiconductor nanowires

V. Cantelli (1) , Olivier Geaymond (2) , O. Ulrich (3) , T. Zhou (1) , Nils Blanc (2) , Gilles Renaud (1)

1 NRS - Nanostructures et Rayonnement Synchrotron
2 NEEL - CRG - CRG & Grands instruments
3 ESRF - European Synchrotron Radiation Facility

The In situ growth of Nanostructures on Surfaces (INS) endstation of the ESRF BM32 beamline: a combined UHV-CVD and MBE reactor for in situ X-ray scattering investigations of growing nanoparticles and semiconductor nanowires This paper presents the upgraded 'In situ growth of Nanoscructures on Surfaces' (INS) endstation of the InterFace beamline IF-BM32 at the European Synchrotron Radiation Facility (ESRF). This instrument, originally designed to investigate the structure of clean surfaces/interfaces/thin-films by surface X-ray diffraction, has been further developed to investigate the formation and evolution of nanostructures by combining small-and wide-angle X-ray scattering methodologies, i.e. grazing-incidence small-angle X-ray scattering (GISAXS) and grazing-incidence X-ray diffraction (GIXD). It consists of a UHV chamber mounted on a z-axis type goniometer, equipped with residual gas analysis, reflection high-energy electron diffraction (RHEED) and Auger electron spectroscopy (AES) to complete the X-ray scattering investigations. The chamber has been developed so as up to eight sources of molecular beam epitaxy (MBE) can be simultaneously mounted to elaborate the nanostructures. A chemical vapor deposition (CVD) setup has been added to expand the range of growing possibilities, in particular to investigate in situ the growth of semiconductor nanowires. This setup is presented in some detail, as well as the first in situ X-ray scattering measurements during the growth of silicon nanowires.

Mots clés: UHV-CVD; GISAXS; IF-BM32; GIRD; nanowires; in situ

Domaines: Chimie-Physique [physics.chem-ph]

V. Cantelli, Olivier Geaymond, O. Ulrich, T. Zhou, Nils Blanc, et al.. The In situ growth of Nanostructures on Surfaces (INS) endstation of the ESRF BM32 beamline: a combined UHV–CVD and MBE reactor for in situ X-ray scattering investigations of growing nanoparticles and semiconductor nanowires. Journal of Synchrotron Radiation, 2015, 22 (3), pp.688-700. ⟨10.1107/s1600577515001605⟩. ⟨hal-02014384⟩