A versatile route to homo-and hetero-bimetallic 5f−5f and 3d−5f complexes supported by a redox active ligand framework

Clément Camp (1) , Davide Toniolo (2) , Julie Andrez (2) , Jacques Pécaut (1) , Marinella Mazzanti (2)

1 CIBEST - Chimie Interface Biologie pour l’Environnement, la Santé et la Toxicologie
2 EPFL - Institute of Chemical Sciences and Engineering, SB, GGEC Station 6

The salt-elimination reaction of the complex [Na2U(bis-salophen)] with metal halides provides an entry to the synthesis of well-defined homobimetallic uranium–uranium and rare heterobimetallic uranium–cobalt and uranium–nickel complexes supported by a redox-active dinucleating ligand.

Domaines: Chimie

Clément Camp, Davide Toniolo, Julie Andrez, Jacques Pécaut, Marinella Mazzanti. A versatile route to homo-and hetero-bimetallic 5f−5f and 3d−5f complexes supported by a redox active ligand framework. Dalton Transactions, 2017, 46 (34), pp.11145--11148. ⟨10.1039/C7DT01993A⟩. ⟨hal-01877469⟩