Tuning the breathing behaviour of MIL-53 by cation mixing

Farid Nouar (1) , Thomas Devic (1) , Hubert Chevreau (1) , Nathalie Guillou (1) , Emma Gibson , Guillaume Clet (2) , Marco Daturi (2) , Alexandre Vimont (2) , Jean-Marc Greneche (3) , Matthew I Breeze , Richard I Walton , Philip L Llewellyne , Christian Serre (1)

1 ILV - Institut Lavoisier de Versailles
2 LCS - Laboratoire catalyse et spectrochimie
3 LPEC - Laboratoire de physique de l'état condensé

A mixed cation MIL-53(Cr-Fe) MOF has been obtained by direct synthesis. Multiple experimental techniques have demonstrated the presence of a genuine mixed phase, leading to a breathing behaviour different from either of the single cation analogues.

Domaines: Chimie

Farid Nouar, Thomas Devic, Hubert Chevreau, Nathalie Guillou, Emma Gibson, et al.. Tuning the breathing behaviour of MIL-53 by cation mixing. Chemical Communications, 2012, 48 (82), pp.10237--10239. ⟨hal-01840342⟩