Reversible transformation from amorphouse Na3Fe3(SO4)2(OH)6 to crystallized NaFe3(SO4)2(OH)6 Jarosite-type hydroxysulfate

M. Gnanavel (1) , O.I. Lebedev (2, 1) , Philippe Bazin (3) , B. Raveau (1) , Valérie Pralong (1)

1 CRISMAT - Laboratoire de cristallographie et sciences des matériaux
2 Electron Microscopy for Materials Science - EMAT (Antwerp, Belgium)
3 LCS - Laboratoire catalyse et spectrochimie

An amorphous iron hydroxysulfate Na3Fe3(SO4)2(OH)6 has been prepared for the first time from sodium insertion into the crystalline phase NaFe3(SO4)2(OH)6. We show that this transformation is completely reversible, leading back to the well crystallized hexagonal phase on oxidation. This material could then be proposed as positive electrode material for Na ion batteries with a reversible capacity of 120 mAh/g at 2.72 V vs Na+/Na.

Mots clés: Sodium iron hydroxysulfate; Na ion batteries; Cathode; NaFe3(SO4)2(OH)6

Domaines: Chimie

M. Gnanavel, O.I. Lebedev, Philippe Bazin, B. Raveau, Valérie Pralong. Reversible transformation from amorphouse Na3Fe3(SO4)2(OH)6 to crystallized NaFe3(SO4)2(OH)6 Jarosite-type hydroxysulfate. Solid State Ionics, 2015, 278, pp.38--42. ⟨10.1016/j.ssi.2015.05.013⟩. ⟨hal-01840215⟩