D. Kashchiev, Nucleation, 2000.
DOI : 10.1007/978-94-011-0137-0_5

M. Ildefonso, N. Candoni, and S. Veesler, Heterogeneous Nucleation in Droplet-Based Nucleation Measurements, Crystal Growth & Design, vol.13, issue.5, pp.2107-2110, 2013.
DOI : 10.1021/cg4001686

URL : https://hal.archives-ouvertes.fr/hal-00843742

R. Grossier, Z. Hammadi, R. Morin, and S. Veesler, Predictive Nucleation of Crystals in Small Volumes and Its Consequences, Physical Review Letters, vol.107, issue.2, p.25504, 2011.
DOI : 10.1209/epl/i1997-00289-y

URL : https://hal.archives-ouvertes.fr/hal-00624848

J. Gibbs, The Collected Works, Thermodynamics, vol.1, 1948.

N. M. Dixit, A. M. Kulkarni, and C. F. Zukoski, Comparison of experimental estimates and model predictions of protein crystal nucleation rates, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol.190, issue.1-2, pp.47-60, 2001.
DOI : 10.1016/S0927-7757(01)00664-1

O. Galkin and P. G. Vekilov, Direct Determination of the Nucleation Rates of Protein Crystals, The Journal of Physical Chemistry B, vol.103, issue.49, pp.10965-10971, 1999.
DOI : 10.1021/jp992786x

O. Galkin and P. G. Vekilov, Are Nucleation Kinetics of Protein Crystals Similar to Those of Liquid Droplets?, Journal of the American Chemical Society, vol.122, issue.1, pp.156-163, 2000.
DOI : 10.1021/ja9930869

T. Wolde, P. R. Frenkel, and D. , Enhancement of Protein Crystal Nucleation by Critical Density Fluctuations, Science, vol.128, issue.5334, pp.1975-1978, 1997.
DOI : 10.1103/PhysRev.184.151

URL : https://dspace.library.uu.nl/bitstream/1874/10434/1/frenkel_97_enhancement_protein_crystal.pdf

V. J. Anderson and H. N. Lekkerkerker, Insights into phase transition kinetics from colloid science, Nature, vol.48, issue.6883, pp.811-815, 2002.
DOI : 10.1351/pac197648040471

URL : https://dspace.library.uu.nl/bitstream/1874/14492/1/1390.pdf

D. Gebauer and H. Cölfen, Prenucleation clusters and non-classical nucleation, Nano Today, vol.6, issue.6, pp.564-584, 2011.
DOI : 10.1016/j.nantod.2011.10.005

URL : http://nbn-resolving.de/urn:nbn:de:bsz:352-174284

P. G. Vekilov, Dense Liquid Precursor for the Nucleation of Ordered Solid Phases from Solution, Crystal Growth & Design, vol.4, issue.4, pp.671-685, 2004.
DOI : 10.1021/cg049977w

D. Erdemir, A. Y. Lee, and A. S. Myerson, Nucleation of Crystals from Solution: Classical and Two-Step Models, Accounts of Chemical Research, vol.42, issue.5, pp.621-629, 2009.
DOI : 10.1021/ar800217x

D. Knezic, J. Zaccaro, and A. S. Myerson, Nucleation Induction Time in Levitated Droplets, The Journal of Physical Chemistry B, vol.108, issue.30, pp.10672-10677, 2004.
DOI : 10.1021/jp049586s

S. Toschev, Homogeneous nucleation Crystal growth: an introduction, pp.1-49, 1973.

R. Boistelle and J. P. Astier, Crystallization mechanisms in solution, Journal of Crystal Growth, vol.90, issue.1-3, pp.14-30, 1988.
DOI : 10.1016/0022-0248(88)90294-1

N. H. Fletcher, Size Effect in Heterogeneous Nucleation, The Journal of Chemical Physics, vol.11, issue.10, pp.572-576, 1958.
DOI : 10.1175/1520-0469(1954)011<0516:HNOSD>2.0.CO;2

D. Kashchiev, D. Verdoes, and G. M. Van-rosmalen, Induction time and metastability limit in new phase formation, Journal of Crystal Growth, vol.110, issue.3, pp.373-380, 1991.
DOI : 10.1016/0022-0248(91)90273-8

O. Galkin and P. G. Vekilov, Direct Determination of the Nucleation Rates of Protein Crystals, The Journal of Physical Chemistry B, vol.103, issue.49, pp.10965-10971, 1999.
DOI : 10.1021/jp992786x

S. Lee and J. Wiener, Visualizing Chemical Phenomena in Microdroplets, Journal of Chemical Education, vol.88, issue.2, pp.151-157, 2010.
DOI : 10.1021/ed100518k

P. Laval, N. Lisai, J. Salmon, and M. Joanicot, A microfluidic device based on droplet storage for screening solubility diagrams, Lab on a Chip, vol.96, issue.7, pp.829-834, 2007.
DOI : 10.1016/j.jcrysgro.2006.12.044

J. Leng and J. Salmon, Microfluidic crystallization, Lab Chip, vol.196, issue.1, pp.24-34, 2009.
DOI : 10.1016/S0022-0248(98)00821-5

P. Laval, J. Salmon, and M. Joanicot, A microfluidic device for investigating crystal nucleation kinetics, Journal of Crystal Growth, vol.303, issue.2, pp.622-628, 2007.
DOI : 10.1016/j.jcrysgro.2006.12.044

URL : http://arxiv.org/pdf/cond-mat/0612526

E. Cacioppo and M. L. Pusey, The solubility of the tetragonal form of hen egg white lysozyme from pH 4.0 to 5.4, Journal of Crystal Growth, vol.114, issue.3, pp.286-292, 1991.
DOI : 10.1016/0022-0248(91)90043-5

M. Ataka and M. Asai, Systematic studies on the crystallization of lysozyme, Journal of Crystal Growth, vol.90, issue.1-3, pp.86-93, 1988.
DOI : 10.1016/0022-0248(88)90302-8

L. Legrand, Two polymorphs of lysozyme nitrate: temperature dependence of their solubility, Acta Crystallographica Section D Biological Crystallography, vol.58, issue.10, pp.1564-1567, 2002.
DOI : 10.1107/S0907444902014403

URL : http://journals.iucr.org/d/issues/2002/10/01/ic0037/ic0037.pdf

A. Y. Lee, I. S. Lee, and A. S. Myerson, Factors Affecting the Polymorphic Outcome of Glycine Crystals Constrained on Patterned Substrates, Chemical Engineering & Technology, vol.22, issue.2, pp.281-285, 2006.
DOI : 10.1002/ceat.200500375

D. Mangin, F. Puel, and S. Veesler, Polymorphism in Processes of Crystallization in Solution: A Practical Review, Organic Process Research & Development, vol.13, issue.6, pp.1241-1253, 2009.
DOI : 10.1021/op900168f

URL : https://hal.archives-ouvertes.fr/hal-00440718

D. Vivares, S. Veesler, J. P. Astier, F. Bonneté, and . Cryst, Polymorphism of Urate Oxidase in PEG Solutions, Crystal Growth & Design, vol.6, issue.1, pp.287-292, 2006.
DOI : 10.1021/cg0500223

URL : https://hal.archives-ouvertes.fr/hal-00016517

K. Allain, R. Bebawee, S. Lee, and . Cryst, in Isolated Microdroplets at Liquid???Liquid Interface, Crystal Growth & Design, vol.9, issue.7, pp.3183-3190, 2009.
DOI : 10.1021/cg801199e

D. Kashchiev, Note: On the critical supersaturation for nucleation, The Journal of Chemical Physics, vol.15, issue.19, pp.196102-196102, 2011.
DOI : 10.1063/1.3559453

R. Grossier, S. Veesler, and . Cryst, Reaching One Single and Stable Critical Cluster through Finite-Sized Systems, Crystal Growth & Design, vol.9, issue.4, pp.1917-1922, 2009.
DOI : 10.1021/cg801165b

URL : https://hal.archives-ouvertes.fr/hal-00386957

D. Voss, The 110% Solution, Science, vol.274, issue.5291, p.1325, 1996.
DOI : 10.1126/science.274.5291.1325

D. W. Oxtoby, Materials chemistry: Crystals in a flash, Nature, vol.6, issue.6913, pp.277-278, 2002.
DOI : 10.1021/jp991439k

R. Gomer, Field emission and field ionization, 1961.