M. O. Andreae, B. E. Anderson, D. R. Blake, J. D. Bradshaw, J. E. Collins et al., Influence of plumes from biomass burning on atmospheric chemistry over the equatorial and tropical South Atlantic during CITE 3, J. Geophys. Res, vol.99, p.12793, 1994.

T. Arakaki, C. Anastasio, Y. Kuroki, H. Nakajima, K. Okada et al., A general scavenging rate constant for reaction of hydroxyl radical with organic carbon in atmospheric waters, Environ. Sci. Technol, vol.47, pp.8196-8203, 2013.

N. Berrojalbiz, J. Dachs, M. J. Ojeda, M. C. Valle, J. Castro-jiménez et al., Biogeochemical and physical controls on concentrations of polycyclic aromatic hydrocarbons in water and plankton of the Mediterranean and Black Seas, Global Biogeochem. Cycles, vol.25, 2011.
URL : https://hal.archives-ouvertes.fr/hal-02083398

S. Bertilsson and L. J. Tranvik, Photochemically produced carboxylic acids as substrates for freshwater bacterioplankton, Limnol. Oceanogr, vol.43, pp.885-895, 1998.

S. Bertilsson and L. J. Tranvik, Photochemical transformation of dissolved organic matter in lakes, Limnol. Oceanogr, vol.45, pp.753-762, 2000.

I. Bouloubassi and A. Saliot, Dissolved, particulate and sedimentary naturally derived polycyclic aromatic hydrocarbons in a coastal environment: geochemical significance, Mar. Chem, vol.42, issue.93, p.90242, 1993.

T. Brinkmann, P. Hörsch, D. Sartorius, and F. H. Frimmel, Photoformation of lowmolecular-weight organic acids from brown water dissolved organic matter, Environ. Sci. Technol, vol.37, pp.4190-4198, 2003.

J. Castro-jiménez, G. Deviller, M. Ghiani, R. Loos, G. Mariani et al., PCDD/F and PCB multi-media ambient concentrations, congener patterns and occurrence in a Mediterranean coastal lagoon, vol.156, pp.123-135, 2008.

J. Castro-jiménez, S. J. Eisenreich, M. Ghiani, G. Mariani, H. Skejo et al., Atmospheric occurrence and deposition of Polychlorinated Dibenzo-pDioxins and Dibenzofurans (PCDD/Fs) in the Open Mediterranean Sea, Environ. Sci. Technol, vol.44, pp.5456-5463, 2010.

J. Castro-jiménez, N. Berrojalbiz, J. Wollgast, and J. Dachs, Polycyclic aromatic hydrocarbons (PAHs) in the Mediterranean Sea: Atmospheric occurrence, deposition and decoupling with settling fluxes in the water column, Environ. Pollut, vol.166, pp.40-47, 2012.

B. C. Crump, B. J. Peterson, P. A. Raymond, R. M. Amon, A. Rinehart et al., Circumpolar synchrony in big river bacterioplankton, 2009.

, Proc. Natl. Acad. Sci, vol.106, pp.21208-21212

J. I. Drever and G. F. Vance, Role of soil organic acids in mineral weathering processes, Organ. Acids in Geol. Proc, 1994.

B. Springer and . Heidelberg, , pp.138-161

X. Durrieu-de-madron, L. Denis, F. Diaz, N. Garcia, C. Guieu et al., Nutrients and carbon budgets for the Gulf of Lion during the Moogli cruises, Oceanol. Acta, vol.26, pp.421-433, 2003.

B. Ervens, CAPRAM 2.4 (MODAC mechanism): an extended and condensed tropospheric aqueous phase mechanism and its application, J. Geophys. Res, vol.108, p.4426, 2003.

B. Ervens, G. Feingold, G. J. Frost, and S. M. Kreidenweis, A modeling of study of aqueous production of dicarboxylic acids: 1. Chemical pathways and speciated organic mass production, J. Geophys. Res. D Atmos, vol.109, pp.1-20, 2004.

F. Eyrolle, O. Radakovitch, P. Raimbault, S. Charmasson, C. Antonelli et al., Consequences of hydrological events on the delivery of suspended sediment and associated radionuclides from the Rh??ne River to the Mediterranean Sea, J. Soils Sediments, vol.12, pp.1479-1495, 2012.

P. Fu, K. Kawamura, K. Usukura, and K. Miura, Dicarboxylic acids, ketocarboxylic acids and glyoxal in the marine aerosols collected during a round-the-world cruise, Mar. Chem, vol.148, pp.22-32, 2013.

A. Gogou, I. Bouloubassi, and E. G. Stephanou, Marine organic geochemistry of the Eastern Mediterranean: 1. Aliphatic and polyaromatic hydrocarbons in Cretan Sea surficial sediments, Mar. Chem, vol.68, pp.82-83, 2000.
URL : https://hal.archives-ouvertes.fr/hal-00170864

J. V. Goldstone, M. J. Pullin, S. Bertilsson, and B. M. Voelker, Reactions of hydroxyl radical with humic substances: bleaching, mineralization, and production of bioavailable carbon substrates, Environ. Sci. Technol, vol.36, pp.364-372, 2002.

C. Guigue, M. Tedetti, N. Ferretto, N. Garcia, L. Méjanelle et al., Spatial and seasonal variabilities of dissolved hydrocarbons in surface waters from the Northwestern Mediterranean Sea: results from one year intensive sampling, Sci. Total Environ, pp.650-662, 2014.
URL : https://hal.archives-ouvertes.fr/hal-00852112

C. Guigue, M. Tedetti, S. Giorgi, and M. Goutx, Occurrence and distribution of hydrocarbons in the surface microlayer and subsurface water from the urban coastal marine area off Marseilles, Northwestern Mediterranean Sea, Mar. Pollut. Bull, vol.62, pp.2741-2752, 2011.
URL : https://hal.archives-ouvertes.fr/hal-00708796

J. I. Hedges, R. G. Keil, and R. Benner, What happens to terrestrial organic matter in the ocean?, Org. Geochem, vol.27, issue.97, pp.66-67, 1997.

N. Hertkorn, R. Benner, M. Frommberger, P. Schmitt-kopplin, M. Witt et al., Characterization of a major refractory component of marine dissolved organic matter, Geochim. Cosmochim. Acta, vol.70, pp.2990-3010, 2006.

P. J. Hernes, A. C. Robinson, and A. K. Aufdenkampe, Fractionation of lignin during leaching and sorption and implications for organic matter, Geophys. Res. Let, vol.34, 2007.

C. Iba?-ez, D. Pont, and N. Prat, Characterization of the Ebre and Rhone estuaries: A basis for defining and classifying salt-wedge estuaries, Limnol. Oceanogr, vol.42, pp.89-101, 1997.

K. Kawamura and R. B. Gagosian, Mid-chain ketocarboxylic acids in the remote marine atmosphere: Distribution patterns and possible formation mechanisms, J. Atmos. Chem, vol.11, pp.107-122, 1990.

K. Kawamura, E. Tachibana, K. Okuzawa, S. G. Aggarwal, Y. Kanaya et al., High abundances of water-soluble dicarboxylic acids, ketocarboxylic acids and a-dicarbonyls in the mountaintop aerosols over the North China Plain during wheat burning season, Atmos. Chem. Phys, vol.13, pp.8285-8302, 2013.

K. Kawamura, K. Yokoyama, Y. Fujii, and O. Watanabe, A Greenland ice core record of low molecular weight dicarboxylic acids, ketocarboxylic acids, and adicarbonyls: a trend from Little Ice Age to the present (1540 to 1989 A.D.), J. Geophys. Res. Atmos, vol.106, pp.1331-1345, 2001.

K. Kawamura, Y. Imai, and L. Barrie, Photochemical production and loss of organic acids in high Arctic aerosols during long-range transport and polar sunrise ozone depletion events, Atmos. Environ, vol.39, pp.599-614, 2005.

K. Kawamura and S. Bikkina, A review of dicarboxylic acids and related compounds in atmospheric aerosols: molecular distributions, sources and transformation, Atmos. Res, vol.170, pp.140-160, 2016.

K. Kawamura and K. Ikushima, Seasonal changes in the distribution of dicarboxylic acids in the urban atmosphere, Environ. Sci. Technol, vol.27, pp.2227-2235, 1993.

K. Kawamura and I. R. Kaplan, Dicarboxylic acids generated by thermal alteration of kerogen and humic acids, Geochim. Cosmochim. Acta, vol.51, pp.90128-90129, 1987.

V. M. Kerminen, C. Ojanen, T. Pakkanen, R. Hillamo, M. Aurela et al., Low-molecular-weight dicarboxylic acids in an urban and rural atmosphere, J. Aerosol Sci, vol.31, pp.63-67, 2000.

A. S. Kester and J. W. Foster, Diterminal oxidation of long-chain alkanes by bacteria, J. Bacteriol, vol.85, pp.859-869, 1963.

D. J. Kieber and K. Mopper, Photochemical formation of glyoxylic and pyruvic acids in seawater, Mar. Chem, vol.21, p.90034, 1987.

R. J. Kieber, L. H. Hydro, and P. J. Seaton, Photooxidation of triglycerides and fatty acids in seawater: implication toward the formation of marine humic substances, Limnol. Oceanogr, vol.42, pp.1454-1462, 1997.

J. T. Kirk, Optics of UV-B radiation in natural water, Arch. Hydrobiol. Beih. Ergebn. Limnol, vol.43, pp.1-16, 1994.

H. A. Krebs and P. D. Weitzman, Krebs' citric acid cycle: half a century and still turning, p.25, 1987.

C. Leboulanger, L. Oriol, H. Jupin, and C. Desolas-gros, Diel variability of glycolate in the eastern tropical Atlantic Ocean, Deep Sea Res. Part I Oceanogr. Res. Pap, vol.44, pp.90-93, 1997.

J. Mack and J. R. Bolton, Photochemistry of nitrite and nitrate in aqueous solution: a review, J. Photochem. Photobiol. A Chem, vol.128, pp.1-13, 1999.

K. Mopper and W. L. Stahovec, Sources and sinks of low molecular weight organic carbonyl compounds in seawater, Mar. Chem, vol.19, issue.86, pp.90052-90058, 1986.

K. Mopper and X. Zhou, Hydroxyl radical photoproduction in the sea and its potential impact on marine processes, Science, vol.250, issue.80, pp.661-664, 1990.

T. Moutin, P. Raimbault, H. L. Golterman, and B. Coste, The input of nutrients by the Rhone River into the Mediterranean Sea: recent observations and comparison with earlier data, Hydrologica, vol.373, issue.374, pp.237-246, 1998.

M. Narukawa, K. Kawamura, S. Li, and J. Bottenheim, Dicarboxylic acids in the Arctic aerosols and snowpacks collected during ALERT, Atmos. Environ, vol.36, pp.126-133, 2000.
DOI : 10.1016/s1352-2310(02)00126-7
URL : https://eprints.lib.hokudai.ac.jp/dspace/bitstream/2115/10511/1/Narukawa%282002AE%292-1.pdf

T. Novakov and C. E. Corrigan, Cloud condensation nucleus activity of the organic component of biomass smoke particles, Geophys. Res. Lett, vol.23, pp.2141-2144, 1996.

P. Ollivier, B. Hamelin, and O. Radakovitch, Seasonal variations of physical and chemical erosion: a three-year survey of the Rhone River (France), Geochim. Cosmochim. Acta, vol.74, pp.907-927, 2010.
URL : https://hal.archives-ouvertes.fr/hal-01061559

S. Opsahl and R. Benner, Photochemical reactivity of dissolved lignin in river and ocean waters, Limnol. Oceanogr, vol.43, pp.1297-1304, 1998.

A. Paluselli, Y. Aminot, S. Net, F. Galgani, and R. Sempéré, Occurrence of phthalate acid esters (PAEs) in the northwestern Mediterranean Sea and the Rhone River, Prog. Oceanogr, vol.163, pp.221-231, 2018.
URL : https://hal.archives-ouvertes.fr/hal-01769499

C. Panagiotopoulos, R. Sempéré, J. Para, P. Raimbault, C. Rabouille et al., The composition and flux of particulate and dissolved carbohydrates from the Rhone River into the Mediterranean Sea, Biogeosciences, vol.9, 2012.
URL : https://hal.archives-ouvertes.fr/hal-00701986

E. T. Peltzer and J. L. Bada, Low molecular weight a-hydroxy carboxylic and dicarboxylic acids in reducing marine sediments, Geochim. Cosmochim. Acta, vol.45, pp.90015-90021, 1981.
DOI : 10.1016/0016-7037(81)90015-6

D. Pont, J. Simonnet, and A. V. Walter, Medium-term changes in suspended sediment delivery to the ocean: consequences of catchment heterogeneity and river management, Estuar. Coast. Shelf Sci, vol.54, pp.1-18, 2002.
URL : https://hal.archives-ouvertes.fr/hal-01681252

M. J. Pullin, S. Bertilsson, J. V. Goldstone, and B. M. Voelker, Effects of sunlight and hydroxyl radical on dissolved organic matter: Bacterial growth efficiency and production of carboxylic acids and other substrates, Limnol. Oceanogr, vol.49, pp.2011-2022, 2004.

C. Rabouille, D. J. Conley, M. H. Dai, W. Cai, C. T. Chen et al., Comparison of hypoxia among four river-dominated ocean margins: the Changjiang (Yangtze), Mississippi, Pearl, and Rhone rivers, Cont. Shelf Res, vol.28, pp.1527-1537, 2008.
DOI : 10.1016/j.csr.2008.01.020

P. A. Raymond, J. W. Mcclelland, R. M. Holmes, A. V. Zhulidov, K. Mull et al., Flux and age of dissolved organic carbon exported to the Arctic Ocean: a carbon isotopic study of the five largest arctic rivers, Global Biogeochem. Cycles, vol.21, 2007.

P. A. Raymond and J. E. Saiers, Event controlled DOC export from forested watersheds, Biogeochemistry, vol.100, pp.197-209, 2010.
DOI : 10.1007/s10533-010-9416-7

M. Rinaldi, S. Decesari, C. Carbone, E. Finessi, S. Fuzzi et al., Evidence of a natural marine source of oxalic acid and a possible link to glyoxal, J. Geophys. Res, vol.116, 2011.

M. Sadaoui, W. Ludwig, F. Bourrin, and P. Raimbault, Controls, budgets and variability of riverine sediment fluxes to the Gulf of Lions, J. Hydrol, vol.540, pp.1002-1015, 2016.
URL : https://hal.archives-ouvertes.fr/hal-01357640

M. Schnitzer, Chapter 1 Humic Substances: Chemistry and Reactions, pp.1-64, 1978.
DOI : 10.1016/s0166-2481(08)70016-3

R. Sempéré, J. Para, M. Tedetti, B. Charrière, and M. Mallet, Variability of solar radiation and CDOM in surface coastal waters of the Northwestern Mediterranean Sea, Photochem. Photobiol, 2015.

R. Sempéré, M. Tedetti, C. Panagiotopoulos, B. Charrière, and F. Van-wambeke, Distribution and bacterial availability of dissolved neutral sugars in the South East Pacific, Biogeosciences Discuss, vol.5, pp.725-750, 2008.

R. Sempéré, B. Charrière, F. Van-wambeke, and G. Cauwet, Carbon inputs of the Rhone River to the Mediterranean Sea: biogeochemical implications, Global Biogeochem. Cycles, vol.14, pp.669-681, 2000.

R. Sempére and K. Kawamura, Comparative distributions of dicarboxylic acids and related polar compounds in snow, rain and aerosols from urban atmosphere, Atmos. Environ, vol.28, issue.94, pp.90123-90129, 1994.

R. Sempéré and K. Kawamura, Trans-hemispheric contribution of C 2-C 10 a, xdicarboxylic acids, and related polar compounds to water-soluble organic carbon in the western Pacific aerosols in relation to photochemical oxidation reactions, Global Biogeochem. Cycles, vol.17, 2003.

R. Sempéré and K. Kawamura, Low molecular weight dicarboxylic acids and related polar compounds in the remote marine rain samples collected from Western Pacific, Atmos. Environ, vol.30, p.436, 1996.

M. Sicre, M. B. Fernandes, and D. Pont, Poly-aromatic hydrocarbon (PAH) inputs from the Rhone River to the Mediterranean Sea in relation with the hydrological cycle: Impact of floods, Mar. Pollut. Bull, vol.56, pp.1935-1942, 2008.

R. G. Spencer, K. D. Butler, and G. R. Aiken, Dissolved organic carbon and chromophoric dissolved organic matter properties of rivers in the USA, J. Geophys. Res. Biogeosciences, vol.117, 2012.

S. M. Steinberg and J. L. Bada, Oxalic, glyoxalic and pyruvic acids in eastern Pacific Ocean waters, J. Mar. Res, vol.42, pp.697-708, 1984.

S. M. Steinberg and J. L. Bada, The determination of a-keto acids and oxalic acid in sea-water by reversed phase liquid chromatographic separation of fluorescent quinoxilinol derivatives, Mar. Chem, vol.11, issue.82, pp.90027-90032, 1982.

E. G. Stephanou and N. Stratigakis, Oxocarboxylic and.alpha.,omega.-dicarboxylic acids: photooxidation products of biogenic unsaturated fatty acids present in urban aerosols, Environ. Sci. Technol, vol.27, pp.1403-1407, 1993.

A. Stubbins, E. Hood, P. A. Raymond, G. R. Aiken, R. L. Sleighter et al., Anthropogenic aerosols as a source of ancient dissolved organic matter in glaciers, Nat. Geosci, vol.5, pp.198-201, 2012.

M. Tedetti, K. Kawamura, M. Narukawa, F. Joux, B. Charrière et al., Hydroxyl radical-induced photochemical formation of dicarboxylic acids from unsaturated fatty acid (oleic acid) in aqueous solution, J. Photochem. Photobiol. A Chem, vol.188, 2007.
URL : https://hal.archives-ouvertes.fr/hal-00164167

M. Tedetti, K. Kawamura, B. Charrière, N. Chevalier, and R. Sempéré, Determination of low molecular weight dicarboxylic and ketocarboxylic acids in seawater samples, Anal. Chem, vol.78, pp.6012-6018, 2006.
URL : https://hal.archives-ouvertes.fr/hal-01999300

X. Guieu, C. Sempéré, R. Conan, P. Cossa, D. Ortenzio et al., Prog. Oceanogr, vol.91, issue.2, pp.97-166, 2011.

U. Map, State of the mediterranean marine and coastal environment, UNEP/MAP-Barcelona Convention, 2012.

P. P. Vaughan and N. V. Blough, Photochemical formation of hydroxyl radical by constituents of natural waters, Environ. Sci. Technol, vol.32, pp.2947-2953, 1998.

P. Warneck, In-cloud chemistry opens pathway to the formation of oxalic acid in the marine atmosphere, Atmos. Environ, vol.37, pp.2423-2427, 2003.

M. Xiao, F. Wu, H. Liao, W. Li, X. Lee et al., Characteristics and distribution of low molecular weight organic acids in the sediment porewaters in Bosten Lake, China. J. Environ. Sci, vol.22, pp.60112-60113, 2010.

S. C. Yoro, C. Panagiotopoulos, and R. Sempéré, Dissolved organic carbon contamination induced by filters and storage bottles, Water Res, vol.33, pp.1956-1959, 1999.
URL : https://hal.archives-ouvertes.fr/hal-00812068

O. C. Zafiriou, J. Joussot-dubien, R. G. Zepp, and R. G. Zika, Photochemistry of natural waters, Environ. Sci. Technol, vol.18, 1984.

X. Zhou and K. Mopper, Photochemical production of low-molecular-weight carbonyl compounds in seawater and surface microlayer and their air-sea exchange, Mar. Chem, vol.56, p.76, 1997.

X. Zhou and K. Mopper, Determination of photochemically produced hydroxyl radicals in seawater and freshwater, Mar. Chem, vol.30, pp.71-88, 1990.