Molecular Design and Control Over the Morphology of Self-Assembled Films on Ionic Substrates

Ania Amrous (1) , Franck Bocquet (1) , Laurent Nony (1) , Franck Para (1) , Christian Loppacher (1) , Simon Lamare (2) , Frank Palmino (2) , Frederic Cherioux (2) , David Gao (3) , Filippo Federici Canova (4, 5) , Matthew B Watkins (4) , Alexander L Shluger (4)

1 IM2NP - Institut des Matériaux, de Microélectronique et des Nanosciences de Provence
2 FEMTO-ST - Franche-Comté Électronique Mécanique, Thermique et Optique - Sciences et Technologies (UMR 6174)
3 UCL - University College of London [London]
4 Department of Physics and Astronomy [UCL London]
5 WPI-AIMR - WPI Advanced Institute for Materials Research

Achieving control over formation of molecular films on insulating substrates is important for designing novel 2D functional materials and devices. To study the main factors governing successful control, organic molecules with interchangeable polar functional groups, a variable length aromatic body, and flexible hydrocarbon chains are designed, synthesized and then deposited on the (001) surfaces of bulk sodium chloride, potassium chloride, and rubidium chloride. The deposited structures are imaged using noncontact atomic force microscopy and modeled using density functional theory. The results show that it is possible to form large-scale, highly ordered, 2D, porous molecular domains (>104 pores), which are stable at room temperature, and to control the size of the 2D pores. Alternatively, it is possible to form line structures or droplets (through molecular dewetting) by altering the molecular structure or changing the substrate lattice constant. Theoretical calculations explain the balance of the molecule–molecule and molecule–surface interactions and the structure and thermodynamic stability of the grown films.

Domaines: Autre [cond-mat.other]; Acoustique [physics.class-ph]; Matériaux; Micro et nanotechnologies/Microélectronique

Ania Amrous, Franck Bocquet, Laurent Nony, Franck Para, Christian Loppacher, et al.. Molecular Design and Control Over the Morphology of Self-Assembled Films on Ionic Substrates. Advanced Materials Interfaces, 2014, 1 (9), pp.1400414. ⟨10.1002/admi.201400414⟩. ⟨hal-01702354⟩