Elaboration of alumina‐zirconia composites: Role of the zirconia content on the microstructure and mechanical properties

Valentina Naglieri (1, 2) , Paola Palmero (3) , Laura Montanaro (2) , Jérome Chevalier (1)

1 MATEIS - Matériaux, ingénierie et science [Villeurbanne]
2 DMSCE - Department of Materials Science and Chemical Engineering
3 Department of Microbial and Molecular Systems (S2M), Laboratory of Food Technology

Alumina-zirconia (AZ) composites are attractive structural materials, which combine the high hardness and Young's modulus of the alumina matrix with additional toughening effects, due to the zirconia dispersion. In this study, AZ composites containing different amounts of zirconia (in the range 5-20 vol %) were prepared by a wet chemical method, consisting on the surface coating of alumina powders by mixing them with zirconium salt aqueous solutions. After spray-drying, powders were calcined at 600 degrees C for 1 h. Green bodies were then prepared by two methods: uniaxial pressing of spray-dried granules and slip casting of slurries, obtained by re-dispersing the spray dried granulates. After pressureless sintering at 1500 degrees C for 1 h, the slip cast samples gave rise to fully dense materials, characterized by a quite homogeneous distribution of ZrO2 grains in the alumina matrix. The microstructure, phase composition, tetragonal to monoclinic transformation behavior and mechanical properties were investigated and are here discussed as a function of the ZrO2 content. The material containing 10 vol % ZrO2 presented a relevant hardness and exhibited the maximum value of K-I0, mainly imputable to the t -> m transformation at the crack tip.

Domaines: Science des matériaux [cond-mat.mtrl-sci]

Valentina Naglieri, Paola Palmero, Laura Montanaro, Jérome Chevalier. Elaboration of alumina‐zirconia composites: Role of the zirconia content on the microstructure and mechanical properties. Materials, 2013, 6 (5), pp.2090--2102. ⟨10.3390/ma6052090⟩. ⟨hal-01670834⟩