Efficient photocatalytic hydrogen production in water using a cobalt(iii) tetraaza-macrocyclic catalyst: electrochemical generation of the low-valent Co(i) species and its reactivity toward proton reduction

Siddhartha Varma (1) , Carmen E. Castillo (2) , Thibaut Stoll (3) , Jérôme Fortage (2) , Allan G. Blackman , Florian Molton (2) , Alain Deronzier (4) , Marie-Noëlle Collomb (2)

1 LIPhy - Laboratoire Interdisciplinaire de Physique [Saint Martin d’Hères]
2 DCM - CIRE - Département de Chimie Moléculaire - Chimie Inorganique Redox
3 DCM - Département de Chimie Moléculaire
4 UGA UFRM - Université Grenoble Alpes - UFR Médecine

Domaines: Chimie

Siddhartha Varma, Carmen E. Castillo, Thibaut Stoll, Jérôme Fortage, Allan G. Blackman, et al.. Efficient photocatalytic hydrogen production in water using a cobalt(iii) tetraaza-macrocyclic catalyst: electrochemical generation of the low-valent Co(i) species and its reactivity toward proton reduction. Physical Chemistry Chemical Physics, 2013, 15 (40), ⟨10.1039/c3cp52641k⟩. ⟨hal-01652626⟩