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Electrografting of diazonium salts: A kinetics study

Abstract : The rates of electrochemical grafting of different diazonium salts on gold are measured by EQCM (Electrochemical Quartz Crystal Microbalance). These rates correlate reasonably well with the σpara Hammett constant, indicating that the partial electrophilic character of the intermediate aryl radical favors attack on the gold surface.
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Submitted on : Monday, November 27, 2017 - 3:23:32 PM
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Sarra Bouden, Jean Pinson, Christine Vautrin-Ul. Electrografting of diazonium salts: A kinetics study. Electrochemistry Communications, Elsevier, 2017, 81, pp.120 - 123. ⟨10.1016/j.elecom.2017.06.007⟩. ⟨hal-01649484⟩



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