Thermal Treatment of Dredged Sediment in a Rotary Kiln: Investigation of Structural Changes

Jocelyn Ramaroson (1) , Moussa Dia (1) , Jean-Louis Dirion (1) , Ange Nzihou (1) , Guy Depelsenaire (2)

1 RAPSODEE - Centre de recherche d'Albi en génie des procédés des solides divisés, de l'énergie et de l'environnement
2 Solvay

Sediment deposits cause the silting of channels, rivers, and lakes. This completely natural phenomenon is exacerbated by the introduction of industrial and urban wastes into the erosion and sedimentation process. Other problems then appear, such as an increased risk of flooding, a reduced capacity for biological purification, and an associated loss of biodiversity. The presence of toxic compounds in the sediments (of industrial, household, or agricultural origin) worsens the situation, and measures must be taken to restore the natural environmental conditions and processes. This study assesses the technology of treating heavy metals from dredged sediments using phosphoric acid (the NOVOSOL process, which was developed by SOLVAY), which aims to convert metals, mainly Pb, Cd, Zn, and Cu, into insoluble metallic phosphates, and (by calcination) to engineer the properties of the final residues for beneficial use. The effectiveness of this treatment was evaluated by creating the chemical reaction, followed by convective drying and maturation of the treated sediment at ambient temperature, and finally by calcination (400-1000 degrees C). This paper focuses on the study of the decomposition of organics and structural change in the sediment during thermal treatment in a rotary kiln. The results showed that the specific surface, the particle size, and the total organic of the sediment are dependent on the calcination parameters such as the residence time, the calcination temperature, and the flow rate. The degradation of the organic compounds is effective at 600 degrees C. An increase in specific surface is observed until 600 degrees C, followed by a significant reduction accompanied by a densification and growth of particles. This increase in specific surface area observed attributed to the formation of pores due mainly to the decomposition of organics and the gas evolve (CO2, H2O, ...) from 600 degrees C to 900 degrees C.

Domaines: Sciences de l'ingénieur [physics]

Jocelyn Ramaroson, Moussa Dia, Jean-Louis Dirion, Ange Nzihou, Guy Depelsenaire. Thermal Treatment of Dredged Sediment in a Rotary Kiln: Investigation of Structural Changes. Industrial and engineering chemistry research, 2012, 51 (21), p.7146-7152. ⟨10.1021/ie203023k⟩. ⟨hal-01632402⟩