Stress relaxation behavior of organically modified montmorillonite filled natural rubber/nitrile rubber nanocomposites

Hanna J. Maria (1) , Nathalie Lyczko (2) , Ange Nzihou (2) , Kuruvilla Joseph (3) , Cherian Mathew (3) , Sabu Thomas (1, 4)

1 School of Chemical Sciences, Mahatma Gandhi University, Kottayam
2 RAPSODEE - Centre de recherche d'Albi en génie des procédés des solides divisés, de l'énergie et de l'environnement
3 UoK - University of Kerala
4 Faculty of Engineering, Universiti Putra Malaysia, Serdang, Selangor

To reduce material consumption, it is important to have reinforced material with longer life time. Incorporation of nanoparticles to reinforce and compatibilize polymer blends is one of the widely undergoing research areas in polymer science technology. A series of natural rubber and nitrile rubber (NR/NBR) nanocomposite vulcanazite, reinforced with two different organically modified clay (OMt) were prepared. To predict the performance of a material over long periods of time, stress relaxation studies with both the reinforced systems were done. The effects of loading, blend composition, filler polarity and temperature on stress relaxation of OMt reinforced NR/NBR nanocomposites were carefully measured. Based on the stress relaxation measurements, it was observed that due to its polarity difference, O1Mt (Mt modified with dimethyl, benzyl, HT modification provided by Southern Clay Products) was preferentially located at the NBR phase while O2Mt (Mt modified with mercapto silane provided by English India Clay) had more affinity with natural rubber in the NR/NBR nanocomposites. The preferential localization of OMt has been analyzed by HRTEM. The nature of interaction of the nanoclay was found to influence the stress relaxation rate. NR/NBR nanocomposites with higher filler loading showed higher rates of relaxation rate due to the presence of more filler-filler interactions. At 70 degrees C, the viscosity ratio was found to influence the reinforcement, and consequently relaxation rate of the 50/50 NR/NBR nanocomposites. It was found that the rearrangements of the polymer chains are dependent on the blend composition, temperature, filler/polymer interactions etc. To explain and predict observed phenomena, the stretched-exponential Kohlrausch equation and Maxwell-Weichert model were used. For both models, the experimental curve fitted well with the theoretical models. (C) 2013 Elsevier B.V. All tights reserved.

Mots clés: Immiscible rubber blends; Organically modified montmorillonite; Natural rubber; Nitrile rubber; Stretched-exponential relaxation; Stress relaxation

Domaines: Sciences de l'ingénieur [physics]

Hanna J. Maria, Nathalie Lyczko, Ange Nzihou, Kuruvilla Joseph, Cherian Mathew, et al.. Stress relaxation behavior of organically modified montmorillonite filled natural rubber/nitrile rubber nanocomposites. Applied Clay Science, 2014, 87, p.120-128. ⟨10.1016/j.clay.2013.10.019⟩. ⟨hal-01625027⟩