F. A. Armstrong, H. A. Heering, and J. Hirst, Reaction of complex metalloproteins studied by protein-film voltammetry, Chemical Society Reviews, vol.26, issue.3, pp.169-179, 1997.
DOI : 10.1039/cs9972600169

C. Léger and P. Bertrand, Direct Electrochemistry of Redox Enzymes as a Tool for Mechanistic Studies, Chemical Reviews, vol.108, issue.7, pp.2379-2438, 2008.
DOI : 10.1021/cr0680742

V. Fourmond and C. Léger, Protein Electrochemistry: Questions and Answers, Adv. Biochem. Eng. Biotechnol. (advanced online publication), vol.48, pp.1-41, 2016.
DOI : 10.1142/p783
URL : https://hal.archives-ouvertes.fr/hal-01413237

V. Fourmond, C. Greco, K. Sybirna, C. Baffert, P. Wang et al., The oxidative inactivation of FeFe hydrogenase reveals the flexibility of the H-cluster, Nature Chemistry, vol.130, issue.4, pp.336-342, 2014.
DOI : 10.1021/ja711187e
URL : https://hal.archives-ouvertes.fr/hal-01481520

J. G. Jacques, B. Burlat, P. Arnoux, M. Sabaty, B. Guigliarelli et al., Kinetics of substrate inhibition of periplasmic nitrate reductase, Biochimica et Biophysica Acta (BBA) - Bioenergetics, vol.1837, issue.10, pp.1801-1809, 2014.
DOI : 10.1016/j.bbabio.2014.05.357
URL : https://hal.archives-ouvertes.fr/hal-01494456

A. Kubas, C. Orain, D. De-sancho, L. Saujet, M. Sensi et al., Mechanism of O2 diffusion and reduction in FeFe hydrogenases, Nature Chemistry, vol.9, issue.1, pp.88-95, 2017.
DOI : 10.1021/ct500594z
URL : https://hal.archives-ouvertes.fr/hal-01406025

C. F. Megarity, J. Esselborn, S. V. Hexter, F. Wittkamp, U. Apfel et al., Electrochemical Investigations of the Mechanism of Assembly of the Active-Site H-Cluster of [FeFe]-Hydrogenases, Journal of the American Chemical Society, vol.138, issue.46, pp.138-184
DOI : 10.1021/jacs.6b09366

S. V. Hexter, F. Grey, T. Happe, V. Climent, and F. A. Armstrong, Electrocatalytic mechanism of reversible hydrogen cycling by enzymes and distinctions between the major classes of hydrogenases, Proc. Natl
DOI : 10.1021/ac8025702

V. Fourmond, C. Baffert, K. Sybirna, T. Lautier, A. Abou-hamdan et al., Steady-State Catalytic Wave-Shapes for 2-Electron Reversible Electrocatalysts and Enzymes, Journal of the American Chemical Society, vol.135, issue.10, pp.3926-393810, 1021.
DOI : 10.1021/ja311607s
URL : https://hal.archives-ouvertes.fr/hal-01268145

V. Fourmond and C. Léger, Modelling the voltammetry of adsorbed enzymes and molecular catalysts, Current Opinion in Electrochemistry (advanced online publication)

H. A. Heering, J. Hirst, and F. A. Armstrong, Interpreting the Catalytic Voltammetry of Electroactive Enzymes Adsorbed on Electrodes, The Journal of Physical Chemistry B, vol.102, issue.35, pp.6889-6902, 1998.
DOI : 10.1021/jp981023r

T. Reda and J. Hirst, Interpreting the Catalytic Voltammetry of an Adsorbed Enzyme by Considering Substrate Mass Transfer, Enzyme Turnover, and Interfacial Electron Transport, The Journal of Physical Chemistry B, vol.110, issue.3, pp.1394-1404, 2006.
DOI : 10.1021/jp054783s

M. Can, F. A. Armstrong, and S. W. Ragsdale, Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase, Chemical Reviews, vol.114, issue.8, pp.4149-4174, 2014.
DOI : 10.1021/cr400461p

H. Dobbek, V. Svetlitchnyi, L. Gremer, R. Huber, and O. Meyer, Crystal Structure of a Carbon Monoxide Dehydrogenase Reveals a [Ni-4Fe-5S] Cluster, Science, vol.293, issue.5533, pp.1281-1285, 2001.
DOI : 10.1126/science.1061500

O. Lazarus, T. W. Woolerton, A. Parkin, M. J. Lukey, E. Reisner et al., Water???Gas Shift Reaction Catalyzed by Redox Enzymes on Conducting Graphite Platelets, Journal of the American Chemical Society, vol.131, issue.40, pp.14154-14155, 2009.
DOI : 10.1021/ja905797w
URL : http://europepmc.org/articles/pmc4893959?pdf=render

A. Parkin, J. Seravalli, K. A. Vincent, S. W. Ragsdale, and F. A. Armstrong, CO Dehydrogenase I on an Electrode, Journal of the American Chemical Society, vol.129, issue.34, pp.10328-10329, 2007.
DOI : 10.1021/ja073643o

V. C. Wang, M. Can, E. Pierce, S. W. Ragsdale, and F. A. Armstrong, A Unified Electrocatalytic Description of the Action of Inhibitors of Nickel Carbon Monoxide Dehydrogenase, Journal of the American Chemical Society, vol.135, issue.6, pp.2198-2206, 2013.
DOI : 10.1021/ja308493k

J. Hadj-saïd, M. Pandelia, C. Léger, V. Fourmond, S. Dementin et al., The Carbon Monoxide Dehydrogenase from Desulfovibrio vulgaris, Biochimica et Biophysica Acta (BBA) - Bioenergetics, vol.1847, issue.12, pp.1574-1583, 2015.
DOI : 10.1016/j.bbabio.2015.08.002

A. J. Bard and L. R. Faulkner, Electrochemical methods: Fundamentals and Applications, 2000.

C. Léger, S. Dementin, P. Bertrand, M. Rousset, and B. Guigliarelli, NiFe Hydrogenase Studied by Protein Film Voltammetry, Journal of the American Chemical Society, vol.126, issue.38, pp.12162-72, 2004.
DOI : 10.1021/ja046548d

C. Orain, L. Saujet, C. Gauquelin, P. Soucaille, I. Meynial-salles et al., Demonstrate That the Reaction Is Partly Reversible, Journal of the American Chemical Society, vol.137, issue.39, pp.12580-12587, 2015.
DOI : 10.1021/jacs.5b06934
URL : https://hal.archives-ouvertes.fr/hal-01211469

D. Wise and G. Houghton, Diffusion coefficients of neon, krypton, xenon, carbon monoxide and nitric oxide in water at 10???60??C, Chemical Engineering Science, vol.23, issue.10, pp.1211-1216, 1968.
DOI : 10.1016/0009-2509(68)89029-3

V. Fourmond, QSoas: A Versatile Software for Data Analysis, Analytical Chemistry, vol.88, issue.10
DOI : 10.1021/acs.analchem.6b00224
URL : https://hal.archives-ouvertes.fr/hal-01414965