Analysis and Testing of Bisphenol A-Free Bio-Based Tannin Epoxy-Acrylic Adhesives

Shayesteh Jahanshahi (1, 2) , Antonio Pizzi (2, 3) , Ali Abdulkhani (1) , Alireza Shakeri (1)

1 University of Tehran
2 LERMAB - Laboratoire d'Etude et de Recherche sur le Matériau Bois
3 King Abdulaziz University

A tannin-based epoxy acrylate resin was prepared from glycidyl ether tannin (GET) and acrylic acid. The influence of the reaction condition for producing tannin epoxy acrylate was studied by FT-MIR, C-13-NMR, MALDI-TOF spectroscopy and shear strength. The best reaction conditions for producing tannin epoxy acrylate resin without bisphenol A was by reaction between GET and acrylic acid in the presence of a catalyst and hydroquinone at 95 degrees C for 12 h. FT-MIR, C-13-NMR and MALDI-TOF analysis have confirmed that the resin has been prepared under these conditions. The joints bonded with this resin were tested for block shear strength. The results obtained indicated that the best strength performance was obtained by the bioepoxy-acrylate adhesive resin prepared at 95 degrees C for a 12-h reaction.

Mots clés: biosourced adhesives; C-13-NMR; FT-MIR; MALDI-TOF; glycidylation; epoxy resin; tannin; biosourced adhesives; epoxy resin; glycidylation; acrylic acid; adhesives; acrylic acid; adhesives; MALDI-TOF; FT-MIR; 13 C-NMR

Domaines: Polymères; Matériaux

Shayesteh Jahanshahi, Antonio Pizzi, Ali Abdulkhani, Alireza Shakeri. Analysis and Testing of Bisphenol A-Free Bio-Based Tannin Epoxy-Acrylic Adhesives. Polymers, 2016, 8 (4), pp.7531-7539. ⟨10.3390/polym8040143⟩. ⟨hal-01599584⟩