Yield: 560 mg (99 %) Mp: 57 °C. 1 H NMR (400 MHz, MeOD) ? 0.73 (t05 (s, 12H), Hz, 3H), 1.10 (m, 16H), 1.54 (q, J = 7.5 Hz, 2H) 1H), 7.27 (s, 2H), 7.99 (s, 1H). 13 C NMR (101 MHz, MeOD) ? 13, pp.2918-716, 1097. ,
H) 13 C NMR (101 MHz, MeOD) 13, 2H), 3.96 (dd, J = 15.3, 7.2 Hz, 2H) found: 554. 2283 (M-Cl -) (calc for C26H45N3O3Pd, pp.2868-2870, 1049. ,
1H, 1 st diastereomer), 6.99 (s, 1H, 1 st diastereomer), 7.00 (s, 1H, 2 nd diastereomer), 7.37 (s, 1H, 1 st diastereomer), 7.39 (s, 1H, 2 nd diastereomer) 13 C NMR (101 MHz, CDCl3) ? 13, st and 2 nd diastereomers), pp.32-33 ,
nd diastereomer), 135.2, 146, 171.6 (1 st and 2 nd References [1] J. Bos, G. Roelfes, pp.135-143, 1978. ,
Enantioselective Artificial Metalloenzymes Based on a Bovine Pancreatic Polypeptide Scaffold, Angewandte Chemie International Edition, vol.127, issue.28, pp.5159-5162, 2009. ,
DOI : 10.1002/anie.200901134
Bioinspired Catalyst Design and Artificial Metalloenzymes, Chemistry - A European Journal, vol.453, issue.17, pp.4680-4698, 2011. ,
DOI : 10.1038/nature06879
Preparation of an Immobilized Lipase-Palladium Artificial Metalloenzyme as Catalyst in the Heck Reaction: Role of the Solid Phase, Advanced Synthesis & Catalysis, vol.10, issue.12, pp.2687-2696, 2015. ,
DOI : 10.1016/0141-0229(88)90018-X
Artificial Metalloenzymes through Cysteine-Selective Conjugation of Phosphines to Photoactive Yellow Protein, ChemBioChem, vol.69, issue.9, pp.1236-1239, 2010. ,
DOI : 10.1002/cbic.201000159
Control of the Coordination Structure of Organometallic Palladium Complexes in an apo-Ferritin Cage, Journal of the American Chemical Society, vol.130, issue.32, pp.10512-10514, 2008. ,
DOI : 10.1021/ja802463a
Artificial Metalloenzymes for Asymmetric Allylic Alkylation on the Basis of the Biotin???Avidin Technology, Angewandte Chemie International Edition, vol.14, issue.4, pp.701-705, 2008. ,
DOI : 10.1007/978-3-642-18537-3
An enantioselective artificial Suzukiase based on the biotin???streptavidin technology, Chem. Sci., vol.115, issue.1, pp.673-677, 2016. ,
DOI : 10.1021/acs.chemrev.5b00162
URL : http://pubs.rsc.org/en/content/articlepdf/2016/sc/c5sc03116h
Catalysis by Palladium Pincer Complexes, Chemical Reviews, vol.111, issue.3, pp.2048-2076, 2011. ,
DOI : 10.1021/cr1002112
URL : http://doi.org/10.1021/cr1002112
Recent Findings in Cyclometallation of meta-Substituted Aryl Ligands by Platinum Group Metal Complexes by Caryl-R Bond Activation (R=H, CR3, SiR3), Chemistry - A European Journal, vol.118, issue.5, pp.759-762, 1998. ,
DOI : 10.1002/(SICI)1521-3765(19980515)4:5<759::AID-CHEM759>3.0.CO;2-K
]. Catalytic Activity in the Heck Reaction, Organometallics, vol.24, issue.1, pp.53-61, 2005. ,
DOI : 10.1021/om040102o
Interactions of ??-lactoglobulin with serotonin and arachidonyl serotonin, Biopolymers, vol.56, issue.12, pp.871-880, 2011. ,
DOI : 10.1021/jf801383m
Improving Quantitative Structure???Activity Relationships through Multiobjective Optimization, Journal of Chemical Information and Modeling, vol.49, issue.10, pp.2290-2302, 2008. ,
DOI : 10.1021/ci9002409
Structural Basis for Enantioselectivity in the Transfer Hydrogenation of a Ketone Catalyzed by an Artificial Metalloenzyme, European Journal of Inorganic Chemistry, vol.16, issue.21, pp.3596-3600 ,
DOI : 10.1021/ja00160a020
Design, Synthesis, and Biological Evaluation of a New Palladium(II) Complex: ??-Lactoglobulin and K562 as Targets, The Journal of Physical Chemistry B, vol.114, issue.10, pp.3639-3647, 2010. ,
DOI : 10.1021/jp909143b
Trans-2,6-bis[(dimethylamino)methyl]phenyl-N,N',C complexes of palladium(II) and platinum(II). Crystal structure of [PtI[MeC6H3(CH2NMe2)2-o,o']]BF4: a cyclohexadienyl carbonium ion with a .sigma.-bonded metal substituent, Journal of the American Chemical Society, vol.104, issue.24, pp.6609-6616, 1982. ,
DOI : 10.1021/ja00388a022
-Acylbenzotriazoles:?? Neutral Acylating Reagents for the Preparation of Primary, Secondary, and Tertiary Amides, The Journal of Organic Chemistry, vol.65, issue.24, pp.8210-8213, 2000. ,
DOI : 10.1021/jo000792f