Nonadiabatic dynamics in polyatomic systems studied by femtosecond time-resolved photoelectron spectroscopy

V Blanchet (1) , A Stolow

1 NRC - National Research Council of Canada

We investigate the use of time-resolved photoelectron spectroscopy for studying nonadiabatic polyatomic dissociation dynamics. In particular, we emphasize the importance of the electronic structure of the ionization continuum in interpreting the results and provide an experimental example of these effects in the dissociation dynamics of the NO dimer. (C) 1998 American Institute of Physics.

Domaines: Agrégats Moléculaires et Atomiques [physics.atm-clus]

V Blanchet, A Stolow. Nonadiabatic dynamics in polyatomic systems studied by femtosecond time-resolved photoelectron spectroscopy. Journal of Chemical Physics, 1998, 108 (11), pp.4371-4374. ⟨10.1063/1.475848⟩. ⟨hal-01582349⟩