Magnetic Bistability and Thermochromism in a Molecular Cu II Chain - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Inorganic Chemistry Année : 2009

Magnetic Bistability and Thermochromism in a Molecular Cu II Chain

Résumé

An original magnetic bistability and a thermochromic transition are observed in a new CuII molecular chain. Thermal structural studies reveal changes in the CuII coordination sphere, driven by a more pronounced Jahn−Teller effect at low temperature. These distortions provoke a gradual color change. The structural study at 10 K shows a dimerization of the molecular chain, in agreement with the abrupt magnetic transition observed at 30 K.

Domaines

Chimie Matériaux
Fichier non déposé

Dates et versions

hal-01579817 , version 1 (31-08-2017)

Identifiants

Citer

Fatima Setifi, Samia Benmansour, Mathieu Marchivie, Gaëlle Dupouy, Smail Triki, et al.. Magnetic Bistability and Thermochromism in a Molecular Cu II Chain. Inorganic Chemistry, 2009, 48 (4), pp.1269 - 1271. ⟨10.1021/ic802292s⟩. ⟨hal-01579817⟩
166 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More