One-step synthesis of conjugated enynenitriles from bromocyanoacetylene

Abstract : The chemical reactivity of bromocyanoacetylene has been evaluated for the first time by making it react with terminal alkynes and secondary amines in the presence of bis( triphenylphosphine) palladium dichloride and copper iodide as co-catalysts. This reaction provides new conjugated enynenitriles stereoselectively in one step in variable yields.
Type de document :
Article dans une revue
Organic and Biomolecular Chemistry, Royal Society of Chemistry, 2017, 15 (28), pp.6050-6056. <10.1039/c6ob02590k>
Liste complète des métadonnées


https://hal-univ-rennes1.archives-ouvertes.fr/hal-01578550
Contributeur : Laurent Jonchère <>
Soumis le : mercredi 13 septembre 2017 - 17:01:39
Dernière modification le : vendredi 15 septembre 2017 - 01:08:41

Identifiants

Citation

Romain Ligny, Etienne S. Gauthier, Manuel Yanez, Thierry Roisnel, Jean-Claude Guillemin, et al.. One-step synthesis of conjugated enynenitriles from bromocyanoacetylene. Organic and Biomolecular Chemistry, Royal Society of Chemistry, 2017, 15 (28), pp.6050-6056. <10.1039/c6ob02590k>. <hal-01578550>

Partager

Métriques

Consultations de la notice

47